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Synthesis, Crystal Structure, Magnetic Properties and 57Fe Mössbauer Spectroscopy of the New Trinuclear [Fe3(4-(2′-hydroxyethyl)-1,2,4-triazole)6(H2O)6](CF3SO3)6 Spin Crossover Compound

Bibliographic reference Garcia, Yann ; Guionneau, Philippe ; Bravic, Georges ; Chasseau, Daniel ; Howard, Judith A. K. ; et. al. Synthesis, Crystal Structure, Magnetic Properties and 57Fe Mössbauer Spectroscopy of the New Trinuclear [Fe3(4-(2′-hydroxyethyl)-1,2,4-triazole)6(H2O)6](CF3SO3)6 Spin Crossover Compound. In: European Journal of Inorganic Chemistry, Vol. 2000, no. 7, p. 1531-1538 (2000)
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  1. [1]O. Kahn, J. P. Launay, Chemtronics 1988, 3, 140.
  2. [2]J. Zarembowitch, O. Kahn, New. J. Chem. 1991, 15, 181.
  3. [3]O. Kahn, Molecular Magnetism, VCH, New York, 1993.
  4. Goodwin Harold A., Spin Transitions in six-coordinate iron(II) complexes, 10.1016/s0010-8545(00)80430-0
  5. Gütlich Philipp, Spin crossover in iron(II)-complexes, Structure and Bonding ISBN:9783540104940 p.83-195, 10.1007/bfb0111269
  6. Gütlich Philipp, Hauser Andreas, Spiering Hartmut, Thermal and Optical Switching of Iron(II) Complexes, 10.1002/anie.199420241
  7. [7]
  8. [7a]P. Gütlich, J. Jung, J. Mol. Struct. 1995, 347, 21. −
  9. [7b]P. Gütlich, J. Jung, H. A. Goodwin, NATO ASI Series C, Kluwer, Dordrecht, The Netherlands, 1996, p. 327. −
  10. [7c]P. Gütlich, J. Jung, Nuovo Cimento Soc. Ital. Fis. D 1996, 18, 107. −
  11. [7d]P. Gütlich, Mol. Cryst. Liq. Cryst. 1997, 305, 17. −
  12. [7e]P. Gütlich, H. Spiering, A. Hauser, in: Inorganic Electronic Structure and Spectroscopy (Eds.: E. I. Solomon, A. B. P. Lever), John Wiley & Sons, Inc., 1999, p. 575.
  13. [8]
  14. [8a]O. Kahn, E. Codjovi, Y. Garcia, P. J. van Koningsbruggen, R. Lapouyade, L. Sommier, Symp. Ser. 1996, 644, 298. −
  15. [8b]O. Kahn, C. Jay-Martinez, Science 1998, 279, 44. −
  16. [8c]O. Kahn, Y. Garcia, J. F. Letard, C. Mathonière, NATO ASI Series, Kluwer, Dordrecht, The Netherlands, 1998, p. 127.
  17. Kahn Olivier, Kröber Jonas, Jay Charlotte, Spin Transition Molecular Materials for displays and data recording, 10.1002/adma.19920041103
  18. Krober Jonas, Codjovi Epiphane, Kahn Olivier, Groliere Francoise, Jay Charlotte, A spin transition system with a thermal hysteresis at room temperature, 10.1021/ja00074a062
  19. Kroeber Jonas, Audiere Jean-Paul, Claude Renee, Codjovi Epiphane, Kahn Olivier, Haasnoot Jaap G., Groliere Francoise, Jay Charlotte, Bousseksou Azzedine, Spin Transitions and Thermal Hysteresis in the Molecular-Based Materials [Fe(Htrz)2(trz)](BF4) and [Fe(Htrz)3](BF4)2.cntdot.H2O (Htrz = 1,2,4-4H-triazole; trz = 1,2,4-triazolato), 10.1021/cm00044a044
  20. Kahn O., Codjovi E., Iron(II)-1,2,4-Triazole Spin Transition Molecular Materials, 10.1098/rsta.1996.0012
  21. [13]E. Codjovi, L. Sommier, O. Kahn, C. Jay, New J. Chem. 1996, 20, 503.
  22. Garcia Yann, van Koningsbruggen Petra J., Codjovi Epiphane, Lapouyade René, Kahn Olivier, Rabardel Louis, Non-classical FeII spin-crossover behaviour leading to an unprecedented extremely large apparent thermal hysteresis of 270 K: application for displays, 10.1039/a701242j
  23. van Koningsbruggen Petra J., Garcia Yann, Codjovi Epiphane, Lapouyade René, Kahn Olivier, Fournès Leopold, Rabardel Louis, Non-classical FeII spin-crossover behaviour in polymeric iron(II) compounds of formula [Fe(NH2trz)3]X2xH2O (NH2trz=4-amino-1,2,4-triazole; X=derivatives of naphthalene sulfonate), 10.1039/a702690k
  24. [16]Y. Garcia, P. J. van Koningsbruggen, R. Lapouyade, L. Rabardel, O. Kahn, M. Wierczorek, R. Bronisz, Z. Ciunik, M. F. Rudolf, C. R. Acad. Sci. Paris 1998, IIc, 523.
  25. Garcia Yann, van Koningsbruggen Petra J., Lapouyade René, Fournès Léopold, Rabardel Louis, Kahn Olivier, Ksenofontov Vadim, Levchenko Georg, Gütlich Philipp, Influences of Temperature, Pressure, and Lattice Solvents on the Spin Transition Regime of the Polymeric Compound [Fe(hyetrz)3]A2·3H2O (hyetrz = 4-(2‘-hydroxyethyl)-1,2,4-triazole and A-= 3-nitrophenylsulfonate), 10.1021/cm980107+
  26. Jay Charlotte, Groliere FrançOise, Kahn O., Kröber J., From Spin Transition to Display and Memory Devices, 10.1080/10587259308042924
  27. [19]V. P. Sinditskii, V. I. Sokol, A. E. Fogel’zang, M. D. Dutov, V. V. Serushkin, M. A. Porai-Koshits, B. S. Svetlov, Russ. J. Inorg. Chem. 1987, 32, 1149.
  28. Garcia Yann, van Koningsbruggen Petra J., Bravic Georges, Guionneau Philippe, Chasseau Daniel, Cascarano Giovanni Luca, Moscovici Jacques, Lambert Katia, Michalowicz Alain, Kahn Olivier, Synthesis, Crystal Structure, EXAFS, and Magnetic Properties ofcatena-Poly[μ-tris(4-(2-hydroxyethyl)-1,2,4-triazole-N1,N2)copper(II)] Diperchlorate Trihydrate:  Relevance with the Structure of the Iron(II) 1,2,4-Triazole Spin Transition Molecular Materials, 10.1021/ic970895p
  29. [21]Y. Garcia, Ph.D. thesis, University of Bordeaux I (France), 1999.
  30. [22]
  31. [22a] G. Vos, R. A. Le Fèbre, R. A. G. de Graaff, J. G. Haasnoot, J. Reedijk, J. Am. Chem. Soc. 1983, 105, 1682. −
  32. [22b] G. Vos, R. A. G. de Graaff, J. G. Haasnoot, A. M. van der Kraan, P. de Vaal, J. Reedijk, Inorg. Chem. 1984, 23, 2905.
  33. Thomann Martina, Kahn Olivier, Guilhem Jean, Varret Francois, Spin Conversion versus Antiferromagnetic Interaction in Iron(II) Trinuclear Species. Crystal Structures and Magnetic Properties of [Fe3(p-MeOptrz)8(H2O)4](BF4)6 and [Fe3(p-MeOprtz)6(H2O)6](tos)6 [p-MeOptrz = 4-(p-Methoxyphenyl)-1,2,4-triazole, tos = tosylate], 10.1021/ic00104a010
  34. Kolnaar Jeroen J. A., van Dijk Gytha, Kooijman Huub, Spek Anthony L., Ksenofontov Vadim G., Gütlich Philipp, Haasnoot Jaap G., Reedijk Jan, Synthesis, Structure, Magnetic Behavior, and Mössbauer Spectroscopy of Two New Iron(II) Spin-Transition Compounds with the Ligand 4-Isopropyl-1,2,4-triazole. X-ray Structure of [Fe3(4-isopropyl-1,2,4-triazole)6(H2O)6](tosylate)6·2H2O, 10.1021/ic9612010
  35. Michalowicz Alain, Moscovici Jacques, Ducourant Bernard, Cracco Denis, Kahn Olivier, EXAFS and X-ray powder diffraction studies of the spin transition molecular materials [Fe(Htrz)2(trz)](BF4) and [Fe(Htrz)3](BF4)2.H2O (Htrz = 1,2,4-4H-triazole; trz = 1,2,4-triazolato), 10.1021/cm00058a013
  36. Knig Edgar, Structural Changes Accompanying Continuous and Discontinuous Spin-State Transitions, Progress in Inorganic Chemistry ISBN:9780470166369 p.527-622, 10.1002/9780470166369.ch6
  37. [27]A. L. Spek, G. Vos, Acta Cryst. 1983, C39, 990.
  38. Vos G., Haasnoot J.G., Verschoor G.C., Reedijk J., Schaminee P.E.L., Linear trinuclear coordination compounds with 4-ethyl-1,2,4-triazole. Structure and magnetic properties, 10.1016/s0020-1693(00)85242-1
  39. [29]J. J. A. Kolnaar, Ph.D. Thesis, University of Leiden, 1998.
  40. Guionneau Philippe, Létard Jean-François, Yufit Dimitrii S., Chasseau Daniel, Bravic Georges, Goeta Andrés E., Howard Judith A. K., Kahn Olivier, Structural approach of the features of the spin crossover transition in iron (II) compounds, 10.1039/a808075e
  41. Mikami Mami, Konno Michiko, Saito Yoshihiko, The structure changes and the spin phase transition mechanism of a spin crossover complex, [Fe(2-pic)3]Cl2·EtOH, 10.1016/0009-2614(79)80715-0
  42. Antolini L., Fabretti A. C., Gatteschi D., Giusti A., Sessoli R., Synthesis, crystal and molecular structure, and magnetic properties of bis[(.mu.-3,5-diamino-1,2,4-triazole-N1,N2-bis(.mu.-3,5-diamino-1,2,4-triazolato-N1,N2)triaquacobalt(II))]cobalt(III) trichloride nonahydrate, 10.1021/ic00025a034
  43. Adler P., Spiering H., Guetlich P., Investigation of the 1A1 .dblharw. 5T2 intersystem crossing dynamics of an iron(II) spin-crossover complex in the solid state by Moessbauer spectroscopy, 10.1021/ic00270a005
  44. Sorai M., Ensling J., Hasselbach K.M., Gütlich P., Mössbauer effect study on low-spin 1A1 ⇌ high spin 5T2 transition in [Fe(2-pic)3]Cl2, 10.1016/0301-0104(77)85023-4
  45. Chang Hsiu Rong, McCusker James K., Toftlund Hans, Wilson Scott R., Trautwein Alfred X., Winkler Heiner, Hendrickson David N., [Tetrakis(2-pyridylmethyl)ethylenediamine]iron(II) perchlorate, the first rapidly interconverting ferrous spin-crossover complex, 10.1021/ja00175a012
  46. König Edgar, Nature and dynamics of the spin-state interconversion in metal complexes, Complex Chemistry (1991) ISBN:9783540534990 p.51-152, 10.1007/3-540-53499-7_2
  47. Bousseksou A., Place C., Linares J., Varret F., Dynamic spin crossover in [Fe(2-BIK)3](ClO4)2 and [Fe(Me22-BIK)3](BF4)2 investigated by Mössbauer spectroscopy, 10.1016/0304-8853(92)90774-i
  48. Lemercier G., Bousseksou A., Verelst M., Varret F., Tuchagues J.P., Dynamic spin-crossover in [FeII(TRIM)2]Cl2 investigated by Mössbauer spectroscopy and magnetic measurements, 10.1016/0304-8853(95)00111-5
  49. Kunkeler Paul J., van Koningsbruggen Petra J., Cornelissen Joost P., van der Horst André N., van der Kraan Adri M., Spek Anthony L., Haasnoot Jaap G., Reedijk Jan, Novel Hybrid Spin Systems of 7,7‘,8,8‘-Tetracyanoquinodimethane (TCNQ) Radical Anions and 4-Amino-3,5-bis(pyridin-2-yl)-1,2,4-triazole (abpt). Crystal Structure of [Fe(abpt)2(TCNQ)2] at 298 and 100 K, Mössbauer Spectroscopy, Magnetic Properties, and Infrared Spectroscopy of the Series [MII(abpt)2(TCNQ)2] (M = Mn, Fe, Co, Ni, Cu, Zn), 10.1021/ja943960s
  50. Janiak Christoph, Scharmann Tobias G., Green Jennifer C., Parkin Richard P. G., Kolm Mario J., Riedel Erwin, Mickler Wulfhard, Elguero José, Charamunt Rosa M., Sanz Dionisia, Effects of Nitrogen Substitution in Poly(Pyrazolyl)Borato Ligands: From Orbital Energy Levels to C–H ⃛ O Hydrogen Bonding, 10.1002/chem.19960020815
  51. [41]SMART Version 4.050. Siemens Analytical X-ray Instruments, Madison WI, U.S.A., 1995.
  52. [42]G. M. Sheldrick, SHELXTL-Plus. Release 4.1. Siemens Analytical X-ray Instruments Inc., Madison WI, U.S.A, 1991.