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Electronic and lattice contributions to the thermal conductivity of graphite intercalation compounds

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Issi, J.-P. Heremans, J. Dresselhaus, M.S.

The stage and temperature dependences of the in-plane thermal conductivity of graphite-FeCl/sub 3/ acceptor intercalation compounds are reported and analyzed, as well as the temperature dependence of a stage-5 potassium donor compound. The measured thermal conductivity is tentatively separated into an electronic contribution, which is dominant at low temperatures, and a lattice contribution, which is dominant around room temperature. Quantitative information is provided about lattice defects which are introduced by intercalation and scatter both electrons and phonons. Below room temperature in the in-plane lattice thermal conductivity is reduced by about an order of magnitude relative to pristine graphite due to an equivalent decrease in boundary scattering length and, to a lesser extent, to point defect scattering. Electron and phonon scattering is only weakly stage dependent. Data for the /b c/-axis thermal conductivity of a stage-2 FeCl/sub 3/ and a stage-5 potassium compound are also presented and discussed.

Document type Article de périodique (Journal article) – Article de recherche
Publication date 1983
Journal information "Physical Review. B, Condensed Matter" - Vol. 27, no. 2, p. 1333-1347 (1983)
Peer reviewed yes
issn 0163-1829
Publication status Publié
Affiliation UCL - Autre
Links
  1. Dresselhaus M.S., Dresselhaus G., Intercalation compounds of graphite, 10.1080/00018738100101367
  2. Boxus J., Poulaert B., Issi J-P., Mazurek H., Dresselhaus M.S., Low temperature thermal conductivity of graphite-FeCl3 intercalation compounds, 10.1016/0038-1098(81)90969-8
  3. B. Poulaert, Extended Abstracts of the 15th Biennial Carbon Conference on Carbon, Philadelphia, 1981
  4. Heremans J., Issi J.-P., Zabala-Martinez I., Shayegan M., Dresselhaus M.S., Thermoelectric properties of a dilute graphite donor intercalation compound, 10.1016/0375-9601(81)90217-6
  5. J.-P. Issi, Physics of Intercalation Compounds (1981)
  6. Heremans J., Shayegan M., Dresselhaus M. S., Issi J -P., High-magnetic-field thermal-conductivity measurements in graphite intercalation compounds, 10.1103/physrevb.26.3338
  7. R. Berman, Thermal Conduction in Solids (1976)
  8. Underhill C., Leung S.Y., Dresselhaus G., Dresselhaus M.S., Infrared and Raman spectroscopy of graphite-ferric chloride, 10.1016/0038-1098(79)90158-3
  9. Shayegan M., Dresselhaus M. S., Dresselhaus G., Shubnikov—de Haas measurements in alkali-metal—graphite intercalation compounds, 10.1103/physrevb.25.4157
  10. Underhill C., Krapchev T., Dresselhaus M.S., Synthesis and characterization of high stage alkali metal donor compounds, 10.1016/0379-6779(80)90031-4
  11. G. K. White, Thermal Conductivity (1969)
  12. J.-P. Issi, Proceedings of the 17th Thermal Conductivity Conductivity Conference, Gaithersburg, Maryland, 1982
  13. Zeller C., Denenstein A., Foley G. M. T., Contactless technique for the measurement of electrical resistivity in anisotropic materials, 10.1063/1.1135889
  14. C. Zeller, Thermal Conductivity (1970)
  15. L. A. Pendrys, Extended Abstracts of the 14th Biennial Conference on Carbon, State College, PA, 1979
  16. Guérard D., Foley G. M. T., Zanini M., Fischer J. E., Electronic structure of donor-type graphite intercalation compounds, 10.1007/bf02723512
  17. Onn David G., Foley G. M. T., Fischer J. E., Electronic properties, resistive anomalies, and phase transitions in the graphite intercalation compounds with K, Rb, and Cs, 10.1103/physrevb.19.6474
  18. Suematsu Hiroyoshi, Higuchi Kohei, Tanuma Sei-ichi, Electronic Properties of Graphite-Potassium intercalation Compounds. II. Resistivity, Hall Effect and Magnetoresistance, 10.1143/jpsj.48.1541
  19. I. L. Spain, Chemistry and Physics of Carbon (1973)
  20. Chieu T. C., Dresselhaus M. S., Endo M., Raman studies of benzene-derived graphite fibers, 10.1103/physrevb.26.5867
  21. F. Rousseaux, Physics of Intercalation Compounds (1981)
  22. M. S. Dresselhaus, Extended Abstracts of the 14th Biennial Conference on Carbon, State College, PA, 1979
  23. Vangelisti Rene, Herold Albert, Action des trihalogenures de chrome sur le graphite: Synthese et etude des composes graphite-chlorure chromique, 10.1016/0008-6223(76)90006-3
  24. A. Hérold, Physics and Chemistry of Materials with Layered Structures (1979)
  25. J. B. Perrachon, Extended Abstracts of the 14th Biennial Conference on Carbon, State College, PA, 1979
  26. E. McRae, Physica, 99B, 489 (1980)
  27. Onn David G, Foley G.M.T, Fischer J.E, Resistivity anomalies and phase transitions in alkali-metal graphite intercalation compounds, 10.1016/0025-5416(77)90045-3
  28. P. G. Klemens, Aust. J. Phys., 6, 405 (1953)
  29. Hove John E., Smith Alan W., Interpretation of the Low-Temperature Thermal Conductivity of Graphite, 10.1103/physrev.104.892
  30. B. Dreyfus, J. Phys. (Paris), 28, 955 (1967)
  31. Kelly B.T., The effect of defects on the basal plane thermal conductivity of a graphite crystal, 10.1016/0008-6223(67)90006-1
  32. Kelly B.T., Theory of the effect of crystallite boundaries on the principal thermal conductivities of highly oriented graphite, 10.1016/0008-6223(68)90052-3
  33. Hooker C. N., Ubbelohde A. R., Young D. A., Thermal Conductance of Graphite in Relation to its Defect Structure, 10.1098/rspa.1963.0194
  34. Hooker C. N., Ubbelohde A. R., Young D. A., Anisotropy of Thermal Conductance in Near-Ideal Graphite, 10.1098/rspa.1965.0049
  35. Al-Jishi R., Dresselhaus G., Lattice-dynamical model for graphite, 10.1103/physrevb.26.4514
  36. Grayson Alexander M., Goshorn David P., Guerard D., Lagrange P., El Makrini M., Onn David G., Synthesis and low temperature specific heat of the graphite intercalation compounds KHgC4 and KHgC8, 10.1016/0379-6779(80)90048-x
  37. Alexander M. Grayson, Goshorn David P., Onn David G., Low-temperature specific heat of the graphite intercalation compounds KC8, CsC8, RbC8, and their parent highly oriented pyrolytic graphite, 10.1103/physrevb.22.4535
  38. N. Daumas, C. R. Acad. Sci. Ser. C, 268, 373 (1969)
  39. Callaway Joseph, Model for Lattice Thermal Conductivity at Low Temperatures, 10.1103/physrev.113.1046
  40. Al-Jishi R., Dresselhaus G., Lattice-dynamical model for alkali-metal—graphite intercalation compounds, 10.1103/physrevb.26.4523
  41. Thomas J.M., Millward G.R., Schlögl R.F., Boehm H.P., Direct imaging of a graphite intercalate: Evidence of interpenetration of ‘stages’ in graphite: Ferric chloride, 10.1016/0025-5408(80)90149-x
  42. Timp G., Dresselhaus M. S., Salamanca-Riba L., Erbil A., Hobbs L. W., Dresselhaus G., Eklund P. C., Iye Y., Electron microscopy study of stage-2 graphite-SbCl5, 10.1103/physrevb.26.2323
  43. A. W. Moore, Chemistry and Physics of Carbon (1973)
  44. Kelly B.T, Gilchrist K.E, The basal thermal conductivity of highly oriented pyrolytic graphite as a function of degree of graphitisation, 10.1016/0008-6223(69)90122-5
  45. B. T. Kelly, Physics of Graphite (1981)
  46. A. de Combarieu, J. Phys. (Paris), 28, 951 (1967)
  47. Tsang D.Z, Dresselhaus M.S, The c-axis electrical conductivity of kish graphite, 10.1016/0008-6223(76)90081-6
  48. J.-P. Issi, Solid State Commun.
  49. D. M. Hwang, Physics of Intercalation Compounds, Vol. 38 of Springer Series in Solid State Sciences (1981)
Bibliographic reference Issi, J.-P. ; Heremans, J. ; Dresselhaus, M.S.. Electronic and lattice contributions to the thermal conductivity of graphite intercalation compounds. In: Physical Review. B, Condensed Matter, Vol. 27, no. 2, p. 1333-1347 (1983)
Permanent URL http://hdl.handle.net/2078.1/66457