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Preparation of Janus nanoparticles from block copolymer thin films using triazolinedione chemistry.

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Poggi, Elio [UCL] Ouvry, Wolfgang [UCL] Ernould, Bruno [UCL] Bourgeois, Jean-Pierre [UCL] Chattopadhyay, Subrata [Ghent University (Belgium)] Gohy, Jean-François [UCL]

A nanostructured thin film obtained from a polystyrene-block-poly(4-vinylpyridine) diblock copolymer was used as a template to produce Janus-type nanoparticles. This was achieved by functionalizing the poly(4-vinylpyridine) microdomains with a diene molecule and by cross-linking them with diiodo compounds. A poly(methacrylate) chain end-functionalized by a triazolinedione group was selectively clicked onto the top of the poly(4-vinylpyridine) microdomains. The Janus nanoparticles were then released in solution by the dissolution of the thin film in a good solvent.

Document type Article de périodique (Journal article) – Article de recherche
Access type Accès libre
Publication date 2017
Language Anglais
Journal information "RSC Advances" - Vol. 7, p. 37048-37054
Peer reviewed yes
Publisher RSC
issn 2046-2069
Publication status Publié
Affiliation UCL - SST-IMCN-BSMA
Links
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Bibliographic reference Poggi, Elio ; Ouvry, Wolfgang ; Ernould, Bruno ; Bourgeois, Jean-Pierre ; Chattopadhyay, Subrata ; et. al. Preparation of Janus nanoparticles from block copolymer thin films using triazolinedione chemistry. . In: RSC Advances, Vol. 7, p. 37048-37054
Permanent URL http://hdl.handle.net/2078.1/193079