User menu

Accès à distance ? S'identifier sur le proxy UCLouvain

First acidic macro-mesocellular aluminosilicate monolithic foams "SiAl(HIPE)" and their catalytic properties

Primary tabs

download
  • Open access
  • PDF
  • 2.34 M
download
  • Open access
  • PDF
  • 794.27 K
Debecker, Damien P. [UCL] Boissiere, Cedric [Université P. et M. Curie, Collège de France, Paris] Laurent, Guillaume [CRPP, Université de Bordeaux 1, France] Huet, Stephanie [CRPP, Université de Bordeaux 1, France] Eliaers, Philippe [CRPP, Université de Bordeaux 1, France] Backov, Renal [CRPP, Université de Bordeaux 1, France]

A new type of acidic macrocellular and mesoporous silica–alumina foam is obtained via a one pot alkaline sol–gel route coupled with a concentrated emulsion-based templating technique. The mixed oxide monolith exhibits high surface acidity, translating into excellent performance in the acid-catalyzed dehydration of bioethanol to ethene.

Document type Article de périodique (Journal article) – Article de recherche
Access type Accès libre
Publication date 2015
Language Anglais
Journal information "Chemical Communications" - Vol. 51, no.74, p. 14018-14021 (2015)
Peer reviewed yes
Publisher R S C Publications
issn 1359-7345
e-issn 1364-548X
Publication status Publié
Affiliation UCL - SST/IMCN/MOST - Molecules, Solids and Reactivity
Links
  1. Corma A., Inorganic Solid Acids and Their Use in Acid-Catalyzed Hydrocarbon Reactions, 10.1021/cr00035a006
  2. Busca Guido, Acid Catalysts in Industrial Hydrocarbon Chemistry, 10.1021/cr068042e
  3. Debecker Damien P., Stoyanova Mariana, Rodemerck Uwe, Eloy Pierre, Léonard Alexandre, Su Bao-Lian, Gaigneaux Eric M., Thermal Spreading As an Alternative for the Wet Impregnation Method: Advantages and Downsides in the Preparation of MoO3/SiO2−Al2O3Metathesis Catalysts, 10.1021/jp1074994
  4. Marvey Bassie B., Extrudate versus Powder Silica Alumina as Support for Re2O7 Catalyst in the Metathesis of Seed Oil-Derivatives – A Comparison, 10.3390/ijms10010213
  5. Bouchmella Karim, Hubert Mutin P., Stoyanova Mariana, Poleunis Claude, Eloy Pierre, Rodemerck Uwe, Gaigneaux Eric M., Debecker Damien P., Olefin metathesis with mesoporous rhenium–silicium–aluminum mixed oxides obtained via a one-step non-hydrolytic sol–gel route, 10.1016/j.jcat.2013.02.016
  6. Hensen Emiel J. M., Poduval Dilip G., van Veen J. A. Rob, Promotion of Thiophene Hydrodesulfurization by Ammonia over Amorphous-Silica−Alumina-Supported CoMo and NiMo Sulfides, 10.1021/ie0611756
  7. Korányi Tamás I., Nagy and János B., 27Al and 29Si NMR studies of alumina and amorphous silica-alumina supported NiW(Mo) HDS catalysts, 10.1007/s11144-005-0252-z
  8. El Maksod Islam Hamdy Abd, Hegazy Eman. Z., Kenawy Sayed. H., Saleh Tamer S., An Environmentally Benign, Highly Efficient Catalytic Reduction of p-Nitrophenol using a Nano-Sized Nickel Catalyst Supported on Silica-Alumina, 10.1002/adsc.200900873
  9. Ezuka Koji, Ohshima Masaaki, Kurokawa Hideki, Miura Hiroshi, Support Effect of Palladium Catalysts for Naphthalene Hydrogenation as Model Hydrogen Storage Process Using Low Grade Hydrogen Containing CO, 10.1627/jpi.52.10
  10. Peeters Elisabeth, Cattenot Martine, Geantet Christophe, Breysse Michèle, Zotin José Luiz, Hydrodenitrogenation on Pt/silica–alumina catalysts in the presence of H2S: Role of acidity, 10.1016/j.cattod.2007.12.127
  11. Ishihara Atsushi, Negura Hirotaka, Hashimoto Tadanori, Nasu Hiroyuki, Catalytic properties of amorphous silica-alumina prepared using malic acid as a matrix in catalytic cracking of n-dodecane, 10.1016/j.apcata.2010.08.027
  12. Ali M.A, Tatsumi T, Masuda T, Development of heavy oil hydrocracking catalysts using amorphous silica-alumina and zeolites as catalyst supports, 10.1016/s0926-860x(02)00121-7
  13. Mokaya Robert, Jones William, Physicochemical Characterisation and Catalytic Activity of Primary Amine Templated Aluminosilicate Mesoporous Catalysts, 10.1006/jcat.1997.1851
  14. Takahashi Ryoji, Sato Satoshi, Sodesawa Toshiaki, Yabuki Miyuki, Silica–Alumina Catalyst with Bimodal Pore Structure Prepared by Phase Separation in Sol–Gel Process, 10.1006/jcat.2001.3196
  15. Kresge C. T., Leonowicz M. E., Roth W. J., Vartuli J. C., Beck J. S., Ordered mesoporous molecular sieves synthesized by a liquid-crystal template mechanism, 10.1038/359710a0
  16. Debecker Damien P., Stoyanova Mariana, Colbeau-Justin Fréderic, Rodemerck Uwe, Boissière Cédric, Gaigneaux Eric M., Sanchez Clément, One-Pot Aerosol Route to MoO3-SiO2-Al2O3 Catalysts with Ordered Super Microporosity and High Olefin Metathesis Activity, 10.1002/anie.201106277
  17. Zhou Xiaofeng, Song Shaotong, Duan Aijun, Zhao Zhen, Gong Yanjun, Wang Xilong, Li Jianmei, Wei Yuechang, Jiang Guiyuan, Liu Jian, Synthesis of Al-Containing Spherical Mesocellular Silica Foams with Different Pore Sizes and Their Applications as Catalyst Supports for Hydrodesulfurization of Dibenzothiophene, 10.1002/cctc.201500365
  18. Colbeau-Justin Frédéric, Boissière Cedric, Chaumonnot Alexandra, Bonduelle Audrey, Sanchez Clément, Aerosol Route to Highly Efficient (Co)Mo/SiO2Mesoporous Catalysts, 10.1002/adfm.201302156
  19. Fujiwara Masahiro, Sakamoto Akinori, Shiokawa Kumi, Patra Astam K., Bhaumik Asim, Mesoporous MFI zeolite material from silica–alumina/epoxy-resin composite material and its catalytic activity, 10.1016/j.micromeso.2010.12.024
  20. Meng Xiangju, Nawaz Faisal, Xiao Feng-Shou, Templating route for synthesizing mesoporous zeolites with improved catalytic properties, 10.1016/j.nantod.2009.06.002
  21. Boissiere Cedric, Grosso David, Chaumonnot Alexandra, Nicole Lionel, Sanchez Clement, Aerosol Route to Functional Nanostructured Inorganic and Hybrid Porous Materials, 10.1002/adma.201001410
  22. Xu Xin, Zhao Tianbo, Qi Jian, Guo Yuntao, Miao Ce, Li Fengyan, Liang Meng, Micrometer-scale macroporous silica–alumina composites with spheric and lathy MFI-type crystals via seed-induced in-situ and layer-by-layer synthetic methods, 10.1016/j.matlet.2010.04.057
  23. Falco Marisa, Retuert Jaime, Hidrobo Alexis, Covarrubias Cristian, Araya Paulo, Sedran Ulises, Catalytic performance of silica-aluminas synthesised with the help of chitosan biopolymer, 10.1016/j.apcata.2009.07.012
  24. Mitchell Sharon, Michels Nina-Luisa, Kunze Karsten, Pérez-Ramírez Javier, Visualization of hierarchically structured zeolite bodies from macro to nano length scales, 10.1038/nchem.1403
  25. Baldovino-Medrano V.G., Le M.T., Van Driessche I., Bruneel E., Alcázar C., Colomer M.T., Moreno R., Florencie A., Farin B., Gaigneaux E.M., Role of shaping in the preparation of heterogeneous catalysts: Tableting and slip-casting of oxidation catalysts, 10.1016/j.cattod.2014.08.030
  26. Ngamcharussrivichai Chawalit, Meechan Warakorn, Ketcong Anawat, Kangwansaichon Kunn, Butnark Suchada, Preparation of heterogeneous catalysts from limestone for transesterification of vegetable oils—Effects of binder addition, 10.1016/j.jiec.2011.05.001
  27. Nijhuis T. Alexander, Beers Annemarie E. W., Vergunst Theo, Hoek Ingrid, Kapteijn Freek, Moulijn Jacob A., Preparation of monolithic catalysts, 10.1081/cr-120001807
  28. Tuler F.E., Banús E.D., Zanuttini M.A., Miró E.E., Milt V.G., Ceramic papers as flexible structures for the development of novel diesel soot combustion catalysts, 10.1016/j.cej.2014.02.083
  29. Sachse A., Hulea V., Finiels A., Coq B., Fajula F., Galarneau A., Alumina-grafted macro-/mesoporous silica monoliths as continuous flow microreactors for the Diels–Alder reaction, 10.1016/j.jcat.2011.12.003
  30. Backov R?nal, Combining soft matter and soft chemistry: integrative chemistry towards designing novel and complex multiscale architectures, 10.1039/b602579j
  31. Sanchez Clément, Belleville Philippe, Popall Michael, Nicole Lionel, Applications of advanced hybrid organic–inorganic nanomaterials: from laboratory to market, 10.1039/c0cs00136h
  32. El Kadib Abdelkrim, Chimenton Ricardo, Sachse Alexander, Fajula François, Galarneau Anne, Coq Bernard, Functionalized Inorganic Monolithic Microreactors for High Productivity in Fine Chemicals Catalytic Synthesis, 10.1002/anie.200805580
  33. Carn Florent, Colin Annie, Achard Marie-France, Deleuze Herv�, Sellier Elisabeth, Birot Marc, Backov R�nal, Inorganic monoliths hierarchically textured via concentrated direct emulsion and micellar templatesElectronic supplementary information (ESI) available: XRD profiles, nitrogen physisorption data and pore size distribution calculated from density functional theory, for the xSi-HIPE0.035 series. See http://www.rsc.org/suppdata/jm/b4/b400984c/, 10.1039/b400984c
  34. Brun Nicolas, Ungureanu Simona, Deleuze Hervé, Backov Rénal, Hybrid foams, colloids and beyond: From design to applications, 10.1039/b920518g
  35. Brun N., Babeau Garcia A., Deleuze H., Achard M.-F., Sanchez C., Durand F., Oestreicher V., Backov R., Enzyme-Based Hybrid Macroporous Foams as Highly Efficient Biocatalysts Obtained through Integrative Chemistry, 10.1021/cm100823d
  36. Ungureanu S., Deleuze H., Babot O., Achard M.-F., Sanchez C., Popa M.I., Backov R., Palladium nanoparticles heterogeneous nucleation within organically grafted silica foams and their use as catalyst supports toward the Suzuki–Miyaura and Mizoroki–Heck coupling reactions, 10.1016/j.apcata.2010.09.025
  37. Ungureanu Simona, Deleuze Hervé, Sanchez Clément, Popa Marcel I., Backov Rénal, First Pd@Organo−Si(HIPE) Open-Cell Hybrid Monoliths Generation Offering Cycling Heck Catalysis Reactions, 10.1021/cm801525c
  38. Brun Nicolas, Babeau-Garcia Annick, Achard Marie-France, Sanchez Clément, Durand Fabien, Laurent Guillaume, Birot Marc, Deleuze Hervé, Backov Rénal, Enzyme-based biohybrid foams designed for continuous flow heterogeneous catalysis and biodiesel production, 10.1039/c1ee01295a
  39. Pega Stéphanie, Boissière Cédric, Grosso David, Azaïs Thierry, Chaumonnot Alexandra, Sanchez Clément, Direct Aerosol Synthesis of Large-Pore Amorphous Mesostructured Aluminosilicates with Superior Acid-Catalytic Properties, 10.1002/anie.200805217
  40. Busca Guido, Metal Oxides as Acid-Base Catalytic Materials, Heterogeneous Catalytic Materials (2014) ISBN:9780444595249 p.103-195, 10.1016/b978-0-444-59524-9.00006-7
  41. Debecker Damien P., Hauwaert Damien, Stoyanova Mariana, Barkschat Axel, Rodemerck Uwe, Gaigneaux Eric M., Opposite effect of Al on the performances of MoO3/SiO2-Al2O3 catalysts in the metathesis and in the partial oxidation of propene, 10.1016/j.apcata.2010.06.021
  42. Debecker Damien P., Stoyanova Mariana, Rodemerck Uwe, Léonard Alexandre, Su Bao-Lian, Gaigneaux Eric M., Genesis of active and inactive species during the preparation of MoO3/SiO2–Al2O3 metathesis catalysts via wet impregnation, 10.1016/j.cattod.2010.07.026
  43. Kennedy Gordon J., Wiench Jerzy W., Pruski Marek, Determination of 27Al–29Si connectivities in zeolites with 2D 27Al→29Si RAPT–CPMG–HETCOR NMR, 10.1016/j.ssnmr.2008.04.002
  44. Hensen E.J.M., Poduval D.G., Magusin P.C.M.M., Coumans A.E., Veen J.A.R. van, Formation of acid sites in amorphous silica-alumina, 10.1016/j.jcat.2009.11.008
  45. Debecker Damien P., Stoyanova Mariana, Rodemerck Uwe, Gaigneaux Eric M., Preparation of MoO3/SiO2–Al2O3 metathesis catalysts via wet impregnation with different Mo precursors, 10.1016/j.molcata.2011.03.011
  46. May M., Asomoza M., Lopez T., Gomez R., Precursor Aluminum Effect in the Synthesis of Sol−Gel Si−Al Catalysts:  FTIR and NMR Characterization, 10.1021/cm970320q
  47. Massiot Dominique, Fayon Franck, Capron Mickael, King Ian, Le Calvé Stéphanie, Alonso Bruno, Durand Jean-Olivier, Bujoli Bruno, Gan Zhehong, Hoatson Gina, Modelling one- and two-dimensional solid-state NMR spectra : Modelling 1D and 2D solid-state NMR spectra, 10.1002/mrc.984
  48. Grey Clare P., Vega Alexander J., Determination of the Quadrupole Coupling Constant of the Invisible Aluminum Spins in Zeolite HY with 1H/27Al TRAPDOR NMR, 10.1021/ja00136a022
  49. Bi Jiandong, Guo Xinwen, Liu Min, Wang Xiangsheng, High effective dehydration of bio-ethanol into ethylene over nanoscale HZSM-5 zeolite catalysts, 10.1016/j.cattod.2009.04.016
  50. Fan Denise, Dai Der-Jong, Wu Ho-Shing, Ethylene Formation by Catalytic Dehydration of Ethanol with Industrial Considerations, 10.3390/ma6010101
  51. Zhang Minhua, Yu Yingzhe, Dehydration of Ethanol to Ethylene, 10.1021/ie401157c
Bibliographic reference Debecker, Damien P. ; Boissiere, Cedric ; Laurent, Guillaume ; Huet, Stephanie ; Eliaers, Philippe ; et. al. First acidic macro-mesocellular aluminosilicate monolithic foams "SiAl(HIPE)" and their catalytic properties. In: Chemical Communications, Vol. 51, no.74, p. 14018-14021 (2015)
Permanent URL http://hdl.handle.net/2078.1/165017