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Roll up nanowire battery from silicon chips.

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Vlad, Alexandru [UCL] Reddy, Arava Leela Mohana [Rice University, Houston] Ajayan, Anakha [Rice University, Houston] Singh, Neelam [Rice University, Houston] Gohy, Jean-François [UCL] Melinte, Sorin [UCL] Ajayan, Pulickel M. [Rice University, Houston]

Here we report an approach to roll out Li-ion battery components from silicon chips by a continuous and repeatable etch-infiltrate-peel cycle. Vertically aligned silicon nanowires etched from recycled silicon wafers are captured in a polymer matrix that operates as Li+ gel-electrolyte and electrode separator and peeled off to make multiple battery devices out of a single wafer. Porous, electrically interconnected copper nanoshells are conformally deposited around the silicon nanowires to stabilize the electrodes over extended cycles and provide efficient current collection. Using the above developed process we demonstrate an operational full cell 3.4 V lithium-polymer silicon nanowire (LIPOSIL) battery which is mechanically flexible and scalable to large dimensions.

Document type Article de périodique (Journal article) – Article de recherche
Access type Accès restreint
Publication date 2012
Language Anglais
Journal information "Proceedings of the National Academy of Sciences of the United States of America" - Vol. 109, no. 38, p. 15168-15173 (2012)
Peer reviewed yes
Publisher National Academy of Sciences
issn 0027-8424
e-issn 1091-6490
Publication status Publié
Affiliations UCL - SST/ICTM/ELEN - Pôle en ingénierie électrique
UCL - SST/IMCN/BSMA - Bio and soft matter
Keywords Nanowire battery ; polymer electrolyte ; core-shell nanowires ; energy storage ; flexible electronics ; waste management
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Bibliographic reference Vlad, Alexandru ; Reddy, Arava Leela Mohana ; Ajayan, Anakha ; Singh, Neelam ; Gohy, Jean-François ; et. al. Roll up nanowire battery from silicon chips.. In: Proceedings of the National Academy of Sciences of the United States of America, Vol. 109, no. 38, p. 15168-15173 (2012)
Permanent URL http://hdl.handle.net/2078.1/117089