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Design of a new and highly effective chiral auxiliary for Diels-Alder reaction of 1-aminodiene.

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Robiette, Raphaël Cheboub-Benchaba, Karima Peeters, Daniel [UCL] Marchand-Brynaert, Jacqueline [UCL]

A theoretical investigation of the facial selectivity of optically active oxazolidin-2-one-substituted dienes has been realized. This analysis enabled the development of (R)-4-phenyloxazolidin-2-thione as a very effective chiral auxiliary for cycloaddition of 1-aminodiene.

Document type Article de périodique (Journal article) – Journal Article
Access type Accès restreint
Publication date 2003
Journal information "The Journal of organic chemistry" - Vol. 68, no. 25, p. 9809-12 (2003)
Peer reviewed yes
issn 0022-3263
Publication status Publié
Affiliation UCL - SC/CHIM - Département de chimie
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Bibliographic reference Robiette, Raphaël ; Cheboub-Benchaba, Karima ; Peeters, Daniel ; Marchand-Brynaert, Jacqueline. Design of a new and highly effective chiral auxiliary for Diels-Alder reaction of 1-aminodiene.. In: The Journal of organic chemistry, Vol. 68, no. 25, p. 9809-12 (2003)
Permanent URL http://hdl.handle.net/2078.1/9683