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Spin crossover in a supramolecular Fe4II [2x2] grid triggered by temperature, pressure and light

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Breuning, Esther [] Ruben, Mario [] Lehn, Jean-Marie [] Renz, Franz [] Garcia, Yann [UCL] Rissanen, Kari []

A multiplex electronic switch on the molecular level has been realized by using a tetranuclear FeII complex of the [2×2] grid type. The four metal ions can be switched stepwise between their high-spin and low-spin states by temperature, pressure, and light, thus representing a triple level, triple switch system as illustrated in the picture.

Document type Article de périodique (Journal article)
Publication date 2000
Language Anglais
Journal information "Angewandte Chemie (International Edition)" - Vol. 39, no. 14, p. 2377 and 2504-2507 (2000)
Peer reviewed yes
issn 1433-7851
e-issn 1521-3773
Publication status Publié
Affiliations University of Mainz (Germany) - Inorganic and Analytical Chemistry
UCL - Autre
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Bibliographic reference Breuning, Esther ; Ruben, Mario ; Lehn, Jean-Marie ; Renz, Franz ; Garcia, Yann ; et. al. Spin crossover in a supramolecular Fe4II [2x2] grid triggered by temperature, pressure and light. In: Angewandte Chemie (International Edition), Vol. 39, no. 14, p. 2377 and 2504-2507 (2000)
Permanent URL http://hdl.handle.net/2078/92634