User menu

A symmetry-breaking spin-state transition in iron(III)

Bibliographic reference Griffin, M. ; Shakespeare, S. ; Shepherd, H. J. ; Harding, C. J. ; Létard, J.-F. ; et. al. A symmetry-breaking spin-state transition in iron(III). In: Angewandte Chemie International Edition, Vol. 50, no. 4, p. 896-900 (2011)
Permanent URL http://hdl.handle.net/2078.1/89497
  1. Gütlich Philipp, Goodwin Harold A., Spin Crossover—An Overall Perspective, Topics in Current Chemistry ISBN:9783540403944 p.1-47, 10.1007/b13527
  2. Létard Jean-François, Guionneau Philippe, Goux-Capes Laurence, Towards Spin Crossover Applications, Topics in Current Chemistry ISBN:3540403957 p.221-249, 10.1007/b95429
  3. Bonhommeau Sébastien, Molnár Gábor, Galet Ana, Zwick Antoine, Real José-Antonio, McGarvey John J., Bousseksou Azzedine, One Shot Laser Pulse Induced Reversible Spin Transition in the Spin-Crossover Complex [Fe(C4H4N2){Pt(CN)4}] at Room Temperature, 10.1002/ange.200500717
  4. Bonhommeau Sébastien, Molnár Gábor, Galet Ana, Zwick Antoine, Real José-Antonio, McGarvey John J., Bousseksou Azzedine, One Shot Laser Pulse Induced Reversible Spin Transition in the Spin-Crossover Complex [Fe(C4H4N2){Pt(CN)4}] at Room Temperature, 10.1002/anie.200500717
  5. Niel Virginie, Thompson Amber L., Muñoz M. Carmen, Galet Ana, Goeta Andrés E., Real José A., Crystalline-State Reaction with Allosteric Effect in Spin-Crossover, Interpenetrated Networks with Magnetic and Optical Bistability, 10.1002/ange.200351853
  6. Niel Virginie, Thompson Amber L., Muñoz M. Carmen, Galet Ana, Goeta Andrés E., Real José A., Crystalline-State Reaction with Allosteric Effect in Spin-Crossover, Interpenetrated Networks with Magnetic and Optical Bistability, 10.1002/anie.200351853
  7. Niel Virginie, Martinez-Agudo José María, Muñoz M. Carmen, Gaspar Ana Belén, Real José Antonio, Cooperative Spin Crossover Behavior in Cyanide-Bridged Fe(II)−M(II) Bimetallic 3D Hofmann-like Networks (M = Ni, Pd, and Pt), 10.1021/ic010259y
  8. Gandolfi Claudio, Moitzi Christian, Schurtenberger Peter, Morgan Grace G., Albrecht Martin, Improved Cooperativity of Spin-Labile Iron(III) Centers by Self-Assembly in Solution, 10.1021/ja806611y
  9. Martinho Paulo N., Harding Charles J., Müller-Bunz Helge, Albrecht Martin, Morgan Grace G., Inducing Spin Crossover in Amphiphilic Iron(III) Complexes, 10.1002/ejic.200901183
  10. Cavallini Massimiliano, Bergenti Ilaria, Milita Silvia, Ruani Giampiero, Salitros Ivan, Qu Zhi-Rong, Chandrasekar Rajadurai, Ruben Mario, Micro- and Nanopatterning of Spin-Transition Compounds into Logical Structures, 10.1002/anie.200802085
  11. Cavallini Massimiliano, Bergenti Ilaria, Milita Silvia, Ruani Giampiero, Salitros Ivan, Qu Zhi-Rong, Chandrasekar Rajadurai, Ruben Mario, Micro- and Nanopatterning of Spin-Transition Compounds into Logical Structures, 10.1002/ange.200802085
  12. Boldog Ishtvan, Gaspar Ana B., Martínez Víctor, Pardo-Ibañez Pablo, Ksenofontov Vadim, Bhattacharjee Ashis, Gütlich Philipp, Real José A., Spin-Crossover Nanocrystals with Magnetic, Optical, and Structural Bistability Near Room Temperature, 10.1002/anie.200801673
  13. Boldog Ishtvan, Gaspar Ana B., Martínez Víctor, Pardo-Ibañez Pablo, Ksenofontov Vadim, Bhattacharjee Ashis, Gütlich Philipp, Real José A., Spin-Crossover Nanocrystals with Magnetic, Optical, and Structural Bistability Near Room Temperature, 10.1002/ange.200801673
  14. Volatron Florence, Catala Laure, Rivière Eric, Gloter Alexandre, Stéphan Odile, Mallah Talal, Spin-Crossover Coordination Nanoparticles, 10.1021/ic800803w
  15. Forestier Thibaut, Mornet Stéphane, Daro Nathalie, Nishihara Taishi, Mouri Shin-ichiro, Tanaka Koichiro, Fouché Olivier, Freysz Eric, Létard Jean-François, Nanoparticles of iron(ii) spin-crossover, 10.1039/b806347h
  16. Forestier Thibaut, Kaiba Abdellah, Pechev Stanislav, Denux Dominique, Guionneau Philippe, Etrillard Céline, Daro Nathalie, Freysz Eric, Létard Jean-François, Nanoparticles of [Fe(NH2-trz)3]Br2⋅3 H2O (NH2-trz=2-Amino-1,2,4-triazole) Prepared by the Reverse Micelle Technique: Influence of Particle and Coherent Domain Sizes on Spin-Crossover Properties, 10.1002/chem.200900297
  17. Köppen H., Müller E.W., Köhler C.P., Spiering H., Meissner E., Gütlich P., Unusual spin-transition anomaly in the crossover system [Fe(2-pic)3]Cl2·EtOH, 10.1016/0009-2614(82)83298-3
  18. Garcia Yann, Kahn Olivier, Rabardel Louis, Chansou Benoit, Salmon Lionel, Tuchagues Jean Pierre, Two-Step Spin Conversion for the Three-Dimensional Compound Tris(4,4‘-bis-1,2,4-triazole)iron(II) Diperchlorate, 10.1021/ic990511q
  19. Boinnard Didier, Bousseksou Azzedine, Dworkin Ary, Savariault Jean Michel, Varret Francois, Tuchagues Jean Pierre, Two-step spin conversion of [FeII(5-NO2-sal-N(1,4,7,10))]: 292, 153, and 103 K x-ray crystal and molecular structure, infrared, magnetic, Moessbauer, calorimetric, and theoretical studies, 10.1021/ic00080a015
  20. Reger Daniel L., Little Christine A., Young Victor G., Pink Maren, Variable-Temperature X-ray Structural Investigation of {Fe[HC(3,5-Me2pz)3]2}(BF4)2(pz = Pyrazolyl Ring):  Observation of a Thermally Induced Spin State Change from All High Spin to an Equal High Spin-Low Spin Mixture, Concomitant with the Onset of Nonmerohedral Twinning, 10.1021/ic010056+
  21. Sheu Chou-Fu, Pillet Sébastien, Lin Yen-Chen, Chen Szu-Miao, Hsu I-Jui, Lecomte Claude, Wang Yu, Magnetostructural Relationship in the Spin-Crossover Complex t-{Fe(abpt)2[N(CN)2]2}: Polymorphism and Disorder Phenomenon, 10.1021/ic800879c
  22. Tang Jinkui, Sánchez Costa José, Smulders Simon, Molnár Gábor, Bousseksou Azzedine, Teat Simon J., Li Yangguang, van Albada Gerard A., Gamez Patrick, Reedijk Jan, Two-Step Spin-Transition Iron(III) Compound with a Wide [High Spin-Low Spin] Plateau, 10.1021/ic801973x
  23. Shongwe Musa S., Al-Rashdi Badria A., Adams Harry, Morris Michael J., Mikuriya Masahiro, Hearne Giovanni R., Thermally Induced Two-Step, Two-Site Incomplete6A1↔2T2Crossover in a Mononuclear Iron(III) Phenolate−Pyridyl Schiff-Base Complex:  A Rare Crystallographic Observation of the Coexistence of PureS=5/2and1/2Metal Centers in the Asymmetric Unit, 10.1021/ic700397u
  24. Clérac Rodolphe, Cotton F. Albert, Dunbar Kim R., Lu Tongbu, Murillo Carlos A., Wang Xiaoping, A New Linear Tricobalt Compound with Di(2-pyridyl)amide (dpa) Ligands:  Two-Step Spin Crossover of [Co3(dpa)4Cl2][BF4], 10.1021/ja994051b
  25. Kahn, Molecular Magnetism, 10 (1993)
  26. Real Jose Antonio, Bolvin Helene, Bousseksou Azzedine, Dworkin Ary, Kahn Olivier, Varret Francois, Zarembowitch Jacqueline, Two-step spin crossover in the new dinuclear compound [Fe(bt)(NCS)2]2bpym, with bt = 2,2'-bi-2-thiazoline and bpym = 2,2'-bipyrimidine: experimental investigation and theoretical approach, 10.1021/ja00038a031
  27. Gaspar Ana B., Ksenofontov Vadim, Reiman Sergey, Gütlich Philipp, Thompson Amber L., Goeta Andrés E., Muñoz M. Carmen, Real José A., Mössbauer Investigation of the Photoexcited Spin States and Crystal Structure Analysis of the Spin-Crossover Dinuclear Complex [{Fe(bt)(NCS)2}2bpym] (bt=2,2′-Bithiazoline, bpym=2,2′-Bipyrimidine), 10.1002/chem.200600559
  28. Klingele Marco H., Moubaraki Boujemaa, Cashion John D., Murray Keith S., Brooker Sally, The first X-ray crystal structure determination of a dinuclear complex trapped in the [low spin–high spin] state: [FeII2(PMAT)2](BF4)4·DMF, 10.1039/b415891a
  29. Wiehl L., Kiel G., Koehler C. P., Spiering H., Guetlich P., Structure determination and investigation of the high-spin .tautm. low-spin transition of tris[2-(aminomethyl)pyridine]iron(2+) dibromide.monoethanol, 10.1021/ic00230a012
  30. Jakobi R., Spiering H., Gütlich P., Thermodynamics of the spin transition in [FexZn1−x(2-pic)3]Cl2 · EtOH, 10.1016/0022-3697(92)90055-i
  31. Gütlich Philipp, Hauser Andreas, Spiering Hartmut, Thermal and Optical Switching of Iron(II) Complexes, 10.1002/anie.199420241
  32. Gütlich Philipp, Hauser Andreas, Spiering Hartmut, Thermisch und optisch schaltbare Eisen(II)-Komplexe, 10.1002/ange.19941062006
  33. Romstedt Harald, Hauser Andreas, Spiering Hartmut, High-spin → low-spin relaxation in the two-step spincrossover compound [Fe(pic)3]Cl2EtOH (pic = 2-picolylamine), 10.1016/s0022-3697(97)00142-x
  34. Chernyshov Dmitry, Hostettler Marc, Törnroos Karl W., Bürgi Hans-Beat, Ordering Phenomena and Phase Transitions in a Spin-Crossover Compound—Uncovering the Nature of the Intermediate Phase of[Fe(2-pic)3]Cl2⋅EtOH, 10.1002/anie.200351834
  35. Chernyshov Dmitry, Hostettler Marc, Törnroos Karl W., Bürgi Hans-Beat, Ordnungsphänomene und Phasenübergänge in einer Spin-Crossover-Verbindung:[Fe(2-pic)3]Cl2⋅EtOH durchläuft eine geordnete Zwischenphase, 10.1002/ange.200351834
  36. Hostettler Marc, Törnroos Karl W., Chernyshov Dmitry, Vangdal Brita, Bürgi Hans-Beat, Challenges in Engineering Spin Crossover: Structures and Magnetic Properties of Six Alcohol Solvates of Iron(II) Tris(2-picolylamine) Dichloride, 10.1002/anie.200460736
  37. Hostettler Marc, Törnroos Karl W., Chernyshov Dmitry, Vangdal Brita, Bürgi Hans-Beat, Engineering von Spin-Crossover-Verbindungen? Strukturen und magnetische Eigenschaften von sechs Alkoholsolvaten des Tris(2-picolylamin)eisen(II)-dichlorids, 10.1002/ange.200460736
  38. Törnroos Karl W., Hostettler Marc, Chernyshov Dmitry, Vangdal Brita, Bürgi Hans-Beat, Interplay of Spin Conversion and Structural Phase Transformations: Re-Entrant Phase Transitions in the 2-Propanol Solvate of Tris(2-picolylamine)iron(II) Dichloride, 10.1002/chem.200600547
  39. Bréfuel  Nicolas, Watanabe Hiroshi, Toupet Loic, Come Jérémy, Matsumoto Naohide, Collet Eric, Tanaka Koichiro, Tuchagues Jean-Pierre, Concerted Spin Crossover and Symmetry Breaking Yield Three Thermally and One Light-Induced Crystallographic Phases of a Molecular Material, 10.1002/ange.200904190
  40. Bréfuel  Nicolas, Watanabe Hiroshi, Toupet Loic, Come Jérémy, Matsumoto Naohide, Collet Eric, Tanaka Koichiro, Tuchagues Jean-Pierre, Concerted Spin Crossover and Symmetry Breaking Yield Three Thermally and One Light-Induced Crystallographic Phases of a Molecular Material, 10.1002/anie.200904190
  41. Fedaoui Dalila, Bouhadja Yacine, Kaiba Abdellah, Guionneau Philippe, Létard Jean-François, Rosa Patrick, Complexation of 2,6-Bis(3-pyrazolyl)pyridine–Bis(thiocyanato)iron(II) with a Bridging 4,4′-Bipyridine: A New Example of a Dinuclear Spin Crossover Complex, 10.1002/ejic.200700708
  42. Kaiba A., Shepherd H. J., Fedaoui D., Rosa P., Goeta A. E., Rebbani N., Létard J. F., Guionneau P., Crystallographic elucidation of purely structural, thermal and light-induced spin transitions in an iron(ii) binuclear complex, 10.1039/b914841h
  43. Bonnet Sylvestre, Siegler Maxime A., Costa José Sánchez, Molnár Gábor, Bousseksou Azzedine, Spek Anthony L., Gamez Patrick, Reedijk Jan, A two-step spin crossover mononuclear iron(ii) complex with a [HS–LS–LS] intermediate phase, 10.1039/b811746b
  44. C c a b c β V 3 ρ calcd −3 Θ max Kα λ ϕ ω [25] μ −1 R wR − −3 C c a b c β V 3 ρ calcd −3 θ max Kα λ ϕ ω [25] μ −1 R wR − −3 www.ccdc.cam.ac.uk/data_request/cif
  45. Bonnet Sylvestre, Molnár Gábor, Sanchez Costa José, Siegler Maxime A., Spek Anthony L., Bousseksou Azedine, Fu Wen-Tian, Gamez Patrick, Reedijk Jan, Influence of Sample Preparation, Temperature, Light, and Pressure on the Two-Step Spin Crossover Mononuclear Compound [Fe(bapbpy)(NCS)2], 10.1021/cm803414q
  46. Bousseksou, J. Phys., 2, 1381 (1992)
  47. Bolvin Hélène, The Neel point for spin-transition systems: toward a two-step transition, 10.1016/0301-0104(96)00241-8
  48. Real José A, Gaspar Ana B, Niel Virginie, Muñoz M.Carmen, Communication between iron(II) building blocks in cooperative spin transition phenomena, 10.1016/s0010-8545(02)00220-5
  49. Bousseksou A., Varret F., Nasser J., Ising-like model for the two step spin-crossover of binuclear molecules, 10.1051/jp1:1993191
  50. Sheldrick George M., A short history ofSHELX, 10.1107/s0108767307043930
  51. Dolomanov Oleg V., Bourhis Luc J., Gildea Richard J., Howard Judith A. K., Puschmann Horst, OLEX2: a complete structure solution, refinement and analysis program, 10.1107/s0021889808042726
  52. Bruno Ian J., Cole Jason C., Edgington Paul R., Kessler Magnus, Macrae Clare F., McCabe Patrick, Pearson Jonathan, Taylor Robin, New software for searching the Cambridge Structural Database and visualizing crystal structures, 10.1107/s0108768102003324