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Application of Fe-57 Emission Mossbauer-spectroscopy To the Investigation of the Physicochemical Consequences of the Double Radioactive Decay Ni-57-]co-57-]fe-57 in the Solid-state

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Devillers, Michel [UCL] Ladrière, Jean [UCL]

Fe-57 emission Mossbauer spectroscopy is shown to be a useful technique for investigating the cumulative recoil and Anger after-effects associated with the double electron capture decay, Ni-57-->Co-57-->Fe-57, in the solid state. Experimental results collected in several types of nickel-containing matrices are surveyed: conducting materials (Ni metal), ionic compounds with monoatomic ligands [potassium trifluoronickelate(II)] and coordination compounds with polyatomic ligands (carboxylates). The consequences produced at a molecular level by the two successive decays in Ni-57-labelled nickel compounds can be analysed provided that a strict methodological approach is followed, which compares with the results obtained on the same compounds doped with Fe-57 or (CO)-C-57. In line with the energetics of the Ni-57 radioactive filiation, recoil of nucleogenic Co-57 atoms is systematically observed in Ni-57-labelled samples when the decay into Co-57 and the subsequent Mossbauer analysis were achieved at low temperatures (<90 K). A pronounced matrix influence related to the stabilization of nucleogenic Fe-n+ species in a nickel-based host lattice is described. The complexity of the emission Mossbauer spectra obtained in nickel(II) carboxylates is shown to reveal cumulative recoil, electronic and seif-radiolytic effects. The influence of the ligands concerned is found to be in line with a 'double autoradiolysis model' taking into account the cumulative effects of the two radioactive decays.

Document type Article de périodique (Journal article) – Article de recherche
Publication date 1994
Language Anglais
Journal information "The Analyst" - Vol. 119, no. 4, p. 589-599 (1994)
Peer reviewed yes
Publisher Royal Soc Chemistry (Cambridge)
issn 0003-2654
e-issn 1364-5528
Publication status Publié
Affiliation UCL - SC/CHIM - Département de chimie
Keywords Mossbauer Spectroscopy ; Electron-capture After-effects ; Ni-57 Decay ; Recoil ; Radiolysis
Links
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Bibliographic reference Devillers, Michel ; Ladrière, Jean. Application of Fe-57 Emission Mossbauer-spectroscopy To the Investigation of the Physicochemical Consequences of the Double Radioactive Decay Ni-57-]co-57-]fe-57 in the Solid-state. In: The Analyst, Vol. 119, no. 4, p. 589-599 (1994)
Permanent URL http://hdl.handle.net/2078.1/63305