Ghosez, Léon
[UCL]
Sainte, Francy
Rivera, M.
Bernard-Henriet, Christiane
[UCL]
Gouverneur, Veronique
3-Alkoxy-2H-azirines 4 have been prepared by treatment of enol ethers 6 with iodine azide followed by base-catalysed elimination of HI and thermolysis of the resulting vinyl azide 5. Azirines 4 readily undergo electrophilic additions, to yield products resulting from cleavage of either the N(1)-C(3) or the N(1)-C(2) bond. Reaction of 4 with trimethylsilyl cyanide yields highly functionalized aziridines 12. Thermolysis of 4 produces C-alkoxy-N-vinylmethanimines.
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Bibliographic reference |
Ghosez, Léon ; Sainte, Francy ; Rivera, M. ; Bernard-Henriet, Christiane ; Gouverneur, Veronique. Synthesis and Reactions of 3-alkoxy-2h-azirines. In: Recueil des Travaux Chimiques des Pays-Bas, Vol. 105, no. 10, p. 456-461 (1986) |
Permanent URL |
http://hdl.handle.net/2078.1/54252 |