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Asymmetric Amination of Carboxylic-acids Via a Diels-alder Strategy

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Gouverneur, Véronique [UCL] Ghosez, Léon [UCL]

2-azadienes 1 which are readily prepared from acyl chlorides react with high facial selectivity with the chiral carbamoyl nitroso dicnophile 2. Reduction and hydrolysis of the adducts yield enantiomerically pure amino acids.

Document type Article de périodique (Journal article) – Article de recherche
Access type Accès restreint
Publication date 1991
Language Anglais
Journal information "Tetrahedron Letters" - Vol. 32, no. 39, p. 5349-5352 (1991)
Peer reviewed yes
Publisher Pergamon-elsevier Science Ltd (Oxford)
issn 0040-4039
e-issn 1873-3581
Publication status Publié
Affiliation UCL - SC/CHIM - Département de chimie
Keywords AMINO ACIDS ; NITROSO COMPOUNDS ; AZADIENES ; CYCLOADDITION ; AMINATION
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Bibliographic reference Gouverneur, Véronique ; Ghosez, Léon. Asymmetric Amination of Carboxylic-acids Via a Diels-alder Strategy. In: Tetrahedron Letters, Vol. 32, no. 39, p. 5349-5352 (1991)
Permanent URL http://hdl.handle.net/2078.1/50889