Bourgeois, Y.
Legras, Roger
[UCL]
Devaux, Jacques
[UCL]
Charlier, Y.
Hedrick, JL.
From earlier experiments it was observed that the reactions of aryl fluoride functional aryl ether ketone oligomers (PEK) with m-aminophenol lead to poor levels of amine incorporation because of side-reactions. In this article, a method is presented to protect the m-aminophenol by converting it into a triarylimine group. This protected m-aminophenol was used together with 4-fluoro,4'-hydroxybenzophenone in a typical poly(aryl ether) synthesis. PEKs of different molecular weights were synthesized with number average molecular weights M(n)) of 2600, 4500, and 5400 g/mol. The deprotection of the triarylimine chain end was carried out by an acid treatment to afford a monofunctional aromatic amine end group, amenable towards copolymerization. (C) 1995 John Wiley and Sons, Inc.
Bibliographic reference |
Bourgeois, Y. ; Legras, Roger ; Devaux, Jacques ; Charlier, Y. ; Hedrick, JL.. Synthesis and Characterization of Aromatic Amine Functional Semicrystalline Aryl Ether Ketone Macromers. In: Journal of Polymer Science. Part A, Polymer Chemistry, Vol. 33, no. 5, p. 779-785 (1995) |
Permanent URL |
http://hdl.handle.net/2078.1/48193 |