User menu

Preparation, Structure and Reactivity of Dinuclear Aminothiolate-bridged Iridium Complexes

Bibliographic reference Fernandez, E. ; Ruiz, A. ; Castillon, S. ; Claver, C. ; Piniella, JF. ; et. al. Preparation, Structure and Reactivity of Dinuclear Aminothiolate-bridged Iridium Complexes. In: Dalton Transactions, , no. 13, p. 2137-2142 (1995)
Permanent URL
  1. Okamoto Ken-ichi, Konno Takumi, Hidaka Jinsai, Aggregation of fac-[Ir(aet)3](aet = 2-aminoethanethiolate) around the [Co II 4O]6+ core. Structures and some properties of spontaneously resolved S-bridged octanuclear complexes [{Ir(aet)3}4M4O]Br6(M4= Co II 4, Zn II 4 or Zn II 2.8Co II 1.2), 10.1039/dt9940000533
  2. Konno Takumi, Okamoto Ken-ichi, Hidaka Jinsai, Preparation, Characterization, and Some Properties of a T-Cage-Type S-Bridged RhIII4ZnII3Heptanuclear Complex with a Defective [Zn3HO]5+Core. Crystal Structure of Spontaneously Resolved [{Rh(aet)3}4Zn3HO]Br5(aet = 2-Aminoethanethiolate), 10.1246/bcsj.67.101
  3. Konno Takumi, Nakamura Kenji, Okamoto Ken-ichi, Hidaka Jinsai, Preparation and Some Properties of Linear-Type S-Bridged IrIIICoIIIIrIIITrinuclear Complexes with 2-Aminoethanethiolate (aet) or L-Cysteinate (L-cys). Crystal Structure ofΔΛ-[Co{Ir(aet)3}2](NO3)3, 10.1246/bcsj.66.2582
  4. Capdevila Mercè, González-Duarte Pilar, Foces-Foces Concha, Cano Félix Hernández, Martínez-Ripoll Martín, Synthesis and characterization of homo- and hetero-nuclear mixed thiolate phosphine complexes with NiII, PdII, and PtII. Crystal and molecular structure of bis[µ-(3-dimethylamino-1-propanethiolato)]-bis{[1,2-bis(diphenylphosphino)-ethane]nickel(II)} tetraphenylborate, 10.1039/dt9900000143
  5. Clegg, J. Chem. Soc., Dalton Trans. (1993)
  6. Clegg William, Fraser Kelly Anne, Duran Núria, González-Duarte Pilar, [(PtMe3)3{μ-I, μ-S(CH2)2NHEt2}2]I, the first platinum thiolate complex with an incomplete cubane structure, 10.1016/s0277-5387(00)80126-6
  7. Oro, New J. Chem., 10, 75 (1986)
  8. Ciriano Miguel A., Pérez-Torrente Jesús J., Oro Luis A., Tiripicchio Antonio, Tiripicchio-Camellini Marisa, Heterotrinuclear angular aggregates of rhodium, iridium, palladium and Group 11 metals. X-Ray structure of the complex [(cod)2Rh2(µ3-C7H4NS2)2Ag(O2ClO2)](cod = cycloocta-1,5-diene), 10.1039/dt9910000255
  9. Bayón J. C., Real J., Claver C., Polo A., Ruiz A., Selective hydroformylation with a recoverable dirhodium µ-thiolato complex, 10.1039/c39890001056
  10. Polo Alfonso, Claver Carmen, Castillon Sergio, Ruiz Aurora, Bayon Juan Carlos, Real Julio, Mealli Carlo, Masi Dante, Regioselective hydroformylation of cyclic vinyl and allyl ethers with rhodium catalysts. Crucial influence of the size of the phosphorus cocatalyst, 10.1021/om00059a015
  11. Polo A., Real J., Claver C., Castillón S., Bayón J. C., Low-pressure selective hydroformylation of 2,3- and 2,5-dihydrofuran with a rhodium catalyst. Unexpected influence of the auxiliary ligand tris(o-t-butylphenyl) phosphite, 10.1039/c39900000600
  12. Polo A., Fernandez E., Claver C., Castillon S., Hydroformylation of glucal derivatives with rhodium catalysts. Crucial influence of the auxiliary ligand tris(ortho-tert-butylphenyl) phosphite, 10.1039/c39920000639
  13. Montauzon, Inorg. Synth., 20, 237 (1980)
  14. Bonnet J. J., Galy J., de Montauzon D., Poilblanc R., Novel dinuclear iridium(I) and mixed iridium(I)-rhodium(I) complexes. X-Ray crystal structure of di-µ-benzenethiolato-bis[dicarbonyliridium(I)], 10.1039/c3977000047b
  15. Cotton, Inorg. Chem., 227, 131 (1988)
  16. de Montauzon Dominique, Kalck Philippe, Poilblanc René, Dinuclear bridged d8 metal complexes, 10.1016/s0022-328x(00)93824-5
  17. Bonnet J. J., de Montauzon D., Poilblanc R., Galy J., Structure moléculaire et cristalline du bis(μ-benzènethiolato)-bis[dicarbonyliridium(I)]: un exemple d'empilement en chaine d'entités dinucléaires, 10.1107/s0567740879005008
  18. Bonnet J. J., Thorez A., Maisonnat A., Galy J., Poilblanc R., Thiolato-bridged dinuclear d8 iridium(I) complexes and their hydrogenation to form dihydridodiiridium(II)(Ir-Ir) complexes. Crystal and molecular structures of [Ir(.mu.-SBu-t)(CO)(P(OMe)3)]2 and of [Ir(H)(.mu.-SBu-t)(CO)(P(OMe)3)]2, 10.1021/ja00514a013
  19. Ph. Kalck in Organometallics in Organic Syntheses, eds. A. de Meijere and H. Tom Dick, Springer, Hamburg, 1987, pp. 297–320.
  20. Pinillos M. Teresa, Elduque Anabel, Oro Luis A., Lahoz Fernando J., Bonati Flavio, Tiripicchio Antonio, Tiripicchio-Camellini Marisa, A flexible framework obtained from oxidative additions upon the binuclear complex [Ir2(µ-pz)(µ-SBut)(CO)2{P(OMe)3}2]: preparation and X-ray structures of [Ir2(µ-pz)(µ-SBut)(µ-L)(CO)2{P(OMe)3}2] and [Ir2(µ-pz)(µ-SBut)(µ-L)I2(CO)2-{P(OMe)3}2](Hpz = pyrazole, L = dimethyl acetylenedicarboxylate), 10.1039/dt9900000989
  21. Ainscough E. W., Robinson S. D., Levison J. J., Transition-metal complexes containing phosphorus ligands. Part V. Synthesis and reactivity of some iridium triaryl phosphite complexes: metal-assisted cleavage of ortho-carbon–hydrogen bonds in co-ordinated triaryl phosphite ligands, 10.1039/j19710003413
  22. Bennett MA, Charles R, Hydrogen abstraction from the coordinated ligand in an iridium-triphenylphosphite complex, 10.1071/ch9710427
  23. Valentine Joan S., A new hydrido-iridium(III) isomer of Ir(PPh3)2(CO)Cl, 10.1039/c39730000857
  24. Tolman Chadwick A., Steric effects of phosphorus ligands in organometallic chemistry and homogeneous catalysis, 10.1021/cr60307a002
  25. Cheney, J. Chem. Soc. A, 3834 (1971)
  26. Kalck Philippe, Bonnet Jean Jacques, Oxidative addition of halogens to thiolato-bridged dinuclear iridium(I) complexes. Preparation of several iridium(II) and iridium(III) species. X-ray structure of Ir2(.mu.-Me3CS)2(CO)2(PMe2Ph)2I2, 10.1021/om00069a019
  27. El Amane Mohamed., Maisonnat Andre., Dahan Francoise., Pince Robert., Poilblanc Rene., Double oxidative addition reaction of dihalomethane to dinuclear iridium(I) complexes: preparation and properties of some methylene bridged diiridium(III) complexes. X-ray structure of [IrI(.mu.-t-BuS)(CO)(P(OMe)3]2[.mu.-CH2], 10.1021/om00123a027
  28. Pinillos, J. Chem. Soc., Dalton Trans., 391 (1991)
  29. Claver Carmen, Fis Joelle, Kalck Philippe, Jaud Joel, Preparation and characterization of the dimetallo ketone complexes Ir2(.mu.-S-tert-Bu)2(.mu.-CO)L2(CO)2I2: crystal and molecular structure of the [iridium] complex where L = trimethylphosphine, 10.1021/ic00268a014
  30. Winkhaus Günter, Singer Hellmut, Iridium(I)-Olefinkomplexe, 10.1002/cber.19660991129
  31. van Leeuwen P.W.N.M., Roobeek C.F., On the mechanism of the nickel-catalysed regioselective cyclodimerization of isoprene, 10.1016/s0040-4020(01)97949-9
  32. North A. C. T., Phillips D. C., Mathews F. S., A semi-empirical method of absorption correction, 10.1107/s0567739468000707
  33. G. M. Sheldrick , SHELXS 86, in Crystallographic Computing, eds. G. M. Sheldrick, C. Krüger and R. Goddard, Oxford University Press, Oxford, 1985, vol. 3, pp. 175–189.
  34. G. M. Sheldrick , SHELXL 93, Program for the Refinement of Crystal Structures from Diffraction Data, University of Göttingen, 1993.