Auwera, J. Vander
Fayt, André
[UCL]
Using a total of 18 unapodized high-resolution (MOPD = 300 and 450 cm) Fourier transform absorption spectra of carbonyl sulfide (P X 9 14.3-60,600 Pa X cm, T=296.0 K), we measured 1340 absolute line intensities in 8 bands (v(1) + v(2)(1) - v(2)(1), 2v(2)(0), 2v(1), 4v(2)(0), + 2v(2)(0), 4v(2)(0), v(3), v(2)(1) + v(3) v(2)(1), V-1 + v(3)) of the main isotopologue, located between 827 and 2939 cm(-1). In addition, we measured 307 absolute line intensities in the v(3) fundamental band of (OCS)-O-16-C-12-S-34 and (OCS)-O-16-C-13-S-32, observed near 2061.45 and 2009.23 cm(-1), respectively. The observed Herman-Wallis dependences are in most cases reproduced by the global model of OCS [E. Rbaihi, A. Belafhal, J. Vander Auwera, S. Naim, and A. Fayt, J. Mol. Spectrosc., 191:32-44, 1998]. The pressure self-broadening parameter was also measured up to J = 83. (c) 2005 Elsevier B.V. All rights reserved.
Bibliographic reference |
Auwera, J. Vander ; Fayt, André. Absolute line intensities for carbonyl sulfide from 827 to 2939 cm(-1). In: Journal of Molecular Structure, Vol. 780-81, p. 134-141 (2006) |
Permanent URL |
http://hdl.handle.net/2078.1/38294 |