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Reactivity of (-)-cytisine and derivatives towards palladium salts. X-ray characterization of a new palladium complex of (-)-cytisine

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Bouquillon, Sandrine Rouden, Jacques Muzart, Jacques Lasne, Marie-Claire Hervieu, Maryvonne Tinant, Bernard [UCL]

Reactivity of (-)-cytisine and substituted cytisines towards PdCl2(MeCN)(2) and Pd(OAC)(2) has been studied. Two complexes of Pd(II), PdCl2((-)-cytisine)(2) and Pd(OAC)(2)((-)-cytisine)(2) were prepared. X-ray analysis of Pd(OAc)(2)((-)-cytisine)(2) revealed a square planar environment of the metal center and a trans geometry. Cytisine and N-methylcytisine have been combinated to Pd(OAc)(2) or PdCl2(MeCN)(2) to catalyze the oxidative kinetic resolution of phenethyl alcohol. (C) 2006 Academie des sciences. Published by Elsevier SAS. All rights reserved.

Document type Article de périodique (Journal article) – Article de recherche
Access type Accès restreint
Publication date 2006
Language Anglais
Journal information "Comptes rendus. Chimie" - Vol. 9, no. 10, p. 1301-1308 (2006)
Peer reviewed yes
Publisher Elsevier France-editions Scientifiques Medicales Elsevier (Paris)
issn 1631-0748
Publication status Publié
Affiliation UCL - SC/CHIM - Département de chimie
Keywords cytisine ; palladium ; complexation ; X-ray analysis ; catalysis
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Bibliographic reference Bouquillon, Sandrine ; Rouden, Jacques ; Muzart, Jacques ; Lasne, Marie-Claire ; Hervieu, Maryvonne ; et. al. Reactivity of (-)-cytisine and derivatives towards palladium salts. X-ray characterization of a new palladium complex of (-)-cytisine. In: Comptes rendus. Chimie, Vol. 9, no. 10, p. 1301-1308 (2006)
Permanent URL http://hdl.handle.net/2078.1/38250