About families of orthogonal polynomials satisfying Heun’s differential equation

We consider special families of orthogonal polynomials satisfying differential equations. Besides known hypergeometric cases, we look especially for Heun's differential equations. We show that such equations are satisfied by orthogonal polynomials related to some classical weight functions modified by Dirac weights or by division of powers of binomials. An appropriate set of biorthogonal rational functions, or 2-point Padé approximations, is also described.