User menu

Accès à distance ? S'identifier sur le proxy UCLouvain

Nanostructured organic radical cathodes from self-assembled nitroxide-containing block copolymer thin films

Primary tabs

download
  • Open access
  • PDF
  • 911.07 K
Hauffman, Guillaume [UCL] Vlad, Alexandru [UCL] Janoschka, T. [IOMC, CEEC, Friedrich Schiller University Jena (Germany)] Schubert, U. S. [CEEC, Friedrich Schiller University Jena (Germany)] Gohy, Jean-François [UCL]

This contribution describes the formation of nanostructured thin film organic radical cathodes. First, the self-assembly of poly(styrene)-block-poly(2,2,6,6-tetramethylpiperidinyloxy-4-yl methacrylate) (PTMA-b-PS) diblock copolymers is detailed. In order to improve the nano-morphology of the immiscible PTMA and PS domains, the effect of thermal and solvent annealing is investigated. The formation of thin films with different morphologies such as cylindrical or lamellar nanostructures is observed depending on the processing conditions. The electrochemical properties of the nanostructured films are further investigated to assess the redox activity of the PTMA domains. Cyclic voltammetry of PTMA-b-PS diblock copolymers, either in dissolved or thin film supported configuration, confirms the reversible redox behavior of the nitroxide radical. Galvanostatic cycling of the thin film nanostructured cathodes reveals good capacity retention with fast charge/discharge response resulting from efficient charge and ion transfer as well as structural integrity. Such nanostructured organic radical cathodes provide opportunities for the fabrication of new generation nanostructured organic radical battery architectures.

Document type Article de périodique (Journal article) – Article de recherche
Access type Accès libre
Publication date 2015
Language Anglais
Journal information "Journal of Materials Chemistry A" - Vol. 3, no.38, p. 19575-19581 (2015)
Peer reviewed yes
Publisher R S C Publications ((United Kingdom) Cambridge)
issn 2050-7488
e-issn 2050-7496
Publication status Publié
Affiliation UCL - SST/IMCN/BSMA - Bio and soft matter
Links
  1. Liang Yanliang, Tao Zhanliang, Chen Jun, Organic Electrode Materials for Rechargeable Lithium Batteries, 10.1002/aenm.201100795
  2. Janoschka Tobias, Hager Martin D., Schubert Ulrich S., Powering up the Future: Radical Polymers for Battery Applications, 10.1002/adma.201203119
  3. Suguro Masahiro, Mori Atsunori, Iwasa Shigeyuki, Nakahara Kentaro, Nakano Kaichiro, Syntheses and Electrochemical Properties of TEMPO Radical Substituted Silicones: Active Material for Organic Radical Batteries, 10.1002/macp.200900251
  4. Armand M., Tarascon J.-M., Building better batteries, 10.1038/451652a
  5. Oyaizu Kenichi, Nishide Hiroyuki, Radical Polymers for Organic Electronic Devices: A Radical Departure from Conjugated Polymers?, 10.1002/adma.200803554
  6. Nakahara K, Iwasa S, Satoh M, Morioka Y, Iriyama J, Suguro M, Hasegawa E, Rechargeable batteries with organic radical cathodes, 10.1016/s0009-2614(02)00705-4
  7. Nishide Hiroyuki, Iwasa Shigeyuki, Pu Yong-Jin, Suga Takeo, Nakahara Kentaro, Satoh Masaharu, Organic radical battery: nitroxide polymers as a cathode-active material, 10.1016/j.electacta.2004.02.052
  8. Nishide, Electrochem. Soc. Interface, 32 (2005)
  9. Nakahara Kentaro, Iriyama Jiro, Iwasa Shigeyuki, Suguro Masahiro, Satoh Masaharu, Cairns Elton J., High-rate capable organic radical cathodes for lithium rechargeable batteries, 10.1016/j.jpowsour.2006.11.045
  10. Nakahara Kentaro, Iriyama Jiro, Iwasa Shigeyuki, Suguro Masahiro, Satoh Masaharu, Cairns Elton J., Al-laminated film packaged organic radical battery for high-power applications, 10.1016/j.jpowsour.2006.10.003
  11. Nakahara Kentaro, Iriyama Jiro, Iwasa Shigeyuki, Suguro Masahiro, Satoh Masaharu, Cairns Elton J., Cell properties for modified PTMA cathodes of organic radical batteries, 10.1016/j.jpowsour.2006.11.044
  12. Li Hui-qiao, Zou Ying, Xia Yong-yao, A study of nitroxide polyradical/activated carbon composite as the positive electrode material for electrochemical hybrid capacitor, 10.1016/j.electacta.2006.08.031
  13. Vlad A., Singh N., Rolland J., Melinte S., Ajayan P. M., Gohy J.-F., Hybrid supercapacitor-battery materials for fast electrochemical charge storage, 10.1038/srep04315
  14. Vlad Alexandru, Rolland Julien, Hauffman Guillaume, Ernould Bruno, Gohy Jean-François, Melt-Polymerization of TEMPO Methacrylates with Nano Carbons Enables Superior Battery Materials, 10.1002/cssc.201500246
  15. Suga Takeo, Takeuchi Shunya, Ozaki Takanori, Sakata Miki, Oyaizu Kenichi, Nishide Hiroyuki, Synthesis of Poly(oxoammonium salt)s and Their Electrical Properties in the Organic Thin Film Device, 10.1246/cl.2009.1160
  16. Yasunori Yonekuta, Takashi Kurata, Hiroyuki Nishide, Radical Polymer and its Nano-sized Thin Film Device, 10.2494/photopolymer.18.39
  17. Sukegawa Takashi, Kai Ayumi, Oyaizu Kenichi, Nishide Hiroyuki, Synthesis of Pendant Nitronyl Nitroxide Radical-Containing Poly(norbornene)s as Ambipolar Electrode-Active Materials, 10.1021/ma302278h
  18. Nakahara Kentaro, Oyaizu Kenichi, Nishide Hiroyuki, Organic Radical Battery Approaching Practical Use, 10.1246/cl.2011.222
  19. Schubert Ulrich S., Polymers for energy storage, 10.1016/j.polymer.2015.05.029
  20. Nesvadba Peter, Bugnon Lucienne, Maire Pascal, Novák Petr, Synthesis of A Novel Spirobisnitroxide Polymer and its Evaluation in an Organic Radical Battery†, 10.1021/cm901374u
  21. Tomlinson Edward P., Hay Martha E., Boudouris Bryan W., Radical Polymers and Their Application to Organic Electronic Devices, 10.1021/ma5014572
  22. Suga Takeo, Pu Yong-Jin, Kasatori Shinji, Nishide Hiroyuki, Cathode- and Anode-Active Poly(nitroxylstyrene)s for Rechargeable Batteries:  p- and n-Type Redox Switching via Substituent Effects, 10.1021/ma0628578
  23. Suga Takeo, Ohshiro Hiroki, Sugita Shuhei, Oyaizu Kenichi, Nishide Hiroyuki, Emerging N-Type Redox-Active Radical Polymer for a Totally Organic Polymer-Based Rechargeable Battery, 10.1002/adma.200803073
  24. Suga Takeo, Sugita Shuhei, Ohshiro Hiroki, Oyaizu Kenichi, Nishide Hiroyuki, p- and n-Type Bipolar Redox-Active Radical Polymer: Toward Totally Organic Polymer-Based Rechargeable Devices with Variable Configuration, 10.1002/adma.201003525
  25. Suga Takeo, Nishide Hiroyuki, Redox-Active Radical Polymers for a Totally Organic Rechargeable Battery, Polymers for Energy Storage and Delivery: Polyelectrolytes for Batteries and Fuel Cells (2012) ISBN:0841226318 p.45-53, 10.1021/bk-2012-1096.ch003
  26. Jähnert Thomas, Janoschka Tobias, Hager Martin D., Schubert Ulrich S., Polymers with n-type nitroxide side groups: Synthesis and electrochemical characterization, 10.1016/j.eurpolymj.2014.06.007
  27. Janoschka Tobias, Teichler Anke, Krieg Andreas, Hager Martin D., Schubert Ulrich S., Polymerization of free secondary amine bearing monomers by RAFT polymerization and other controlled radical techniques, 10.1002/pola.25907
  28. Hauffman Guillaume, Rolland Julien, Bourgeois Jean-Pierre, Vlad Alexandru, Gohy Jean-François, Synthesis of nitroxide-containing block copolymers for the formation of organic cathodes, 10.1002/pola.26279
  29. Sukegawa Takashi, Omata Hajime, Masuko Issei, Oyaizu Kenichi, Nishide Hiroyuki, Anionic Polymerization of 4-Methacryloyloxy-TEMPO Using an MMA-Capped Initiator, 10.1021/mz400644y
  30. Rostro Lizbeth, Baradwaj Aditya G., Boudouris Bryan W., Controlled Radical Polymerization and Quantification of Solid State Electrical Conductivities of Macromolecules Bearing Pendant Stable Radical Groups, 10.1021/am403223s
  31. Lin Hsiao-Chien, Li Chia-Chen, Lee Jyh-Tsung, Nitroxide polymer brushes grafted onto silica nanoparticles as cathodes for organic radical batteries, 10.1016/j.jpowsour.2011.05.037
  32. Lin Chun-Hao, Chou Wei-Jen, Lee Jyh-Tsung, Three-Dimensionally Ordered Macroporous Nitroxide Polymer Brush Electrodes Prepared by Surface-Initiated Atom Transfer Polymerization for Organic Radical Batteries, 10.1002/marc.201100548
  33. Wang Yu-Hsuan, Hung Miao-Ken, Lin Chun-Hao, Lin Hsiao-Chien, Lee Jyh-Tsung, Patterned nitroxide polymer brushes for thin-film cathodes in organic radical batteries, 10.1039/c0cc02442b
  34. Ernould Bruno, Devos Marine, Bourgeois Jean-Pierre, Rolland Julien, Vlad Alexandru, Gohy Jean-François, Grafting of a redox polymer onto carbon nanotubes for high capacity battery materials, 10.1039/c5ta00570a
  35. Takahashi Katsuyuki, Korolev Konstantine, Tsuji Kazumasa, Oyaizu Kenichi, Nishide Hiroyuki, Bryuzgin Evgeny, Navrotskiy Alexander, Novakov Ivan, Facile grafting-onto-preparation of block copolymers of TEMPO and glycidyl methacrylates on an oxide substrate as an electrode-active layer, 10.1016/j.polymer.2015.02.043
  36. Suga Takeo, Takeuchi Shunya, Nishide Hiroyuki, Morphology-Driven Modulation of Charge Transport in Radical/Ion-Containing, Self-Assembled Block Copolymer Platform, 10.1002/adma.201103222
  37. Zhuang Xiuli, Xiao Chunsheng, Oyaizu Kenichi, Chikushi Natsuru, Chen Xuesi, Nishide Hiroyuki, Synthesis of amphiphilic block copolymers bearing stable nitroxyl radicals, 10.1002/pola.24345
  38. Hauffman Guillaume, Maguin Quentin, Bourgeois Jean-Pierre, Vlad Alexandru, Gohy Jean-François, Micellar Cathodes from Self-Assembled Nitroxide-Containing Block Copolymers in Battery Electrolytes, 10.1002/marc.201300532
  39. Rostro Lizbeth, Baradwaj Aditya G., Muller Alexander R., Laster Jennifer S., Boudouris Bryan W., Synthesis and thin-film self-assembly of radical-containing diblock copolymers, 10.1557/mrc.2015.27
  40. Suga Takeo, Sakata Miki, Aoki Kohei, Nishide Hiroyuki, Synthesis of Pendant Radical- and Ion-Containing Block Copolymers via Ring-Opening Metathesis Polymerization for Organic Resistive Memory, 10.1021/mz500273z
  41. Liedel Clemens, Moehle Austin, Fuchs Gregory D., Ober Christopher K., Block copolymers with stable radical and fluorinated groups by ATRP, 10.1557/mrc.2015.50
  42. Fredrickson G H, Bates F S, Dynamics of Block Copolymers: Theory and Experiment, 10.1146/annurev.ms.26.080196.002441
  43. BATES F. S., Polymer-Polymer Phase Behavior, 10.1126/science.251.4996.898
  44. Fukunaga Kenji, Elbs Hubert, Magerle Robert, Krausch Georg, Large-Scale Alignment of ABC Block Copolymer Microdomains via Solvent Vapor Treatment, 10.1021/ma9910639
  45. Fukunaga Kenji, Hashimoto Takeji, Elbs Hubert, Krausch Georg, Self-Assembly of a Lamellar ABC Triblock Terpolymer Thin Film. Effect of Substrates, 10.1021/ma021096f
  46. Kim G., Libera M., Morphological Development in Solvent-Cast Polystyrene−Polybutadiene−Polystyrene (SBS) Triblock Copolymer Thin Films, 10.1021/ma971349i
  47. Kim S. H., Misner M. J., Xu T., Kimura M., Russell T. P., Highly Oriented and Ordered Arrays from Block Copolymers via Solvent Evaporation, 10.1002/adma.200304906
  48. R. Gronheid and P.Nealey, Directed Self-assembly of Block Copolymers for Nano-manufacturing, WoodHead Publishing, 1st edn, 2015
  49. Park Soojin, Kim Bokyung, Xu Ji, Hofmann Tommy, Ocko Benjamin M., Russell Thomas P., Lateral Ordering of Cylindrical Microdomains Under Solvent Vapor, 10.1021/ma802480s
  50. Kim Jin Kon, Yang Seung Yun, Lee Youngmin, Kim Youngsuk, Functional nanomaterials based on block copolymer self-assembly, 10.1016/j.progpolymsci.2010.06.002
  51. Pavlishchuk Vitaly V, Addison Anthony W, Conversion constants for redox potentials measured versus different reference electrodes in acetonitrile solutions at 25°C, 10.1016/s0020-1693(99)00407-7
  52. Laoire Cormac O., Plichta Edward, Hendrickson Mary, Mukerjee Sanjeev, Abraham K.M., Electrochemical studies of ferrocene in a lithium ion conducting organic carbonate electrolyte, 10.1016/j.electacta.2009.06.041
Bibliographic reference Hauffman, Guillaume ; Vlad, Alexandru ; Janoschka, T. ; Schubert, U. S. ; Gohy, Jean-François. Nanostructured organic radical cathodes from self-assembled nitroxide-containing block copolymer thin films. In: Journal of Materials Chemistry A, Vol. 3, no.38, p. 19575-19581 (2015)
Permanent URL http://hdl.handle.net/2078.1/169504