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Double thermoresponsive di- and triblock copolymers based on N-vinylcaprolactam and N-vinylpyrrolidone: Synthesis and comparative study of solution behaviour

Bibliographic reference Kermagoret, A. ; Mathieu, K. ; Thomassin, J.-M. ; Fustin, Charles-André ; Duchêne, Roland ; et. al. Double thermoresponsive di- and triblock copolymers based on N-vinylcaprolactam and N-vinylpyrrolidone: Synthesis and comparative study of solution behaviour. In: Polymer Chemistry, Vol. 5, no.22, p. 6534-6544 (2014)
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  1. Liu Fang, Urban Marek W., Recent advances and challenges in designing stimuli-responsive polymers, 10.1016/j.progpolymsci.2009.10.002
  2. Smith Adam E., Xu Xuewei, McCormick Charles L., Stimuli-responsive amphiphilic (co)polymers via RAFT polymerization, 10.1016/j.progpolymsci.2009.11.005
  3. Roy Debashish, Cambre Jennifer N., Sumerlin Brent S., Future perspectives and recent advances in stimuli-responsive materials, 10.1016/j.progpolymsci.2009.10.008
  4. Alarcón Carolina de las Heras, Pennadam Sivanand, Alexander Cameron, Stimuli responsive polymers for biomedical applications, 10.1039/b406727d
  5. Hoffman Allan S., Stimuli-responsive polymers: Biomedical applications and challenges for clinical translation, 10.1016/j.addr.2012.11.004
  6. GIL E, HUDSON S, Stimuli-reponsive polymers and their bioconjugates, 10.1016/j.progpolymsci.2004.08.003
  7. Roy Debashish, Brooks William L. A., Sumerlin Brent S., New directions in thermoresponsive polymers, 10.1039/c3cs35499g
  8. Aseyev Vladimir, Tenhu Heikki, Winnik Françoise M., Non-ionic Thermoresponsive Polymers in Water, Advances in Polymer Science (2010) ISBN:9783642222962 p.29-89, 10.1007/12_2010_57
  9. Dimitrov Ivaylo, Trzebicka Barbara, Müller Axel H.E., Dworak Andrzej, Tsvetanov Christo B., Thermosensitive water-soluble copolymers with doubly responsive reversibly interacting entities, 10.1016/j.progpolymsci.2007.07.001
  10. Yusa Shin-Ichi, Awa Shigeki, Ito Masanori, Kawase Takeshi, Takada Tadao, Nakashima Kenichi, Liu Dian, Yamago Shigeru, Morishima Yotaro, Solubilization of C60 by micellization with a thermoresponsive block copolymer in water: Characterization, singlet oxygen generation, and DNA photocleavage, 10.1002/pola.24709
  11. Reinicke Stefan, Espeel Pieter, Stamenović Milan M., Du Prez Filip E., One-Pot Double Modification of p(NIPAAm): A Tool for Designing Tailor-Made Multiresponsive Polymers, 10.1021/mz4002222
  12. Clark E.A., Lipson J.E.G., LCST and UCST behavior in polymer solutions and blends, 10.1016/j.polymer.2011.11.045
  13. Lutz Jean-François, Thermo-Switchable Materials Prepared Using the OEGMA-Platform, 10.1002/adma.201100597
  14. Vancoillie Gertjan, Frank Daniel, Hoogenboom Richard, Thermoresponsive poly(oligo ethylene glycol acrylates), 10.1016/j.progpolymsci.2014.02.005
  15. Wang Yu-Cai, Xia Hai, Yang Xian-Zhu, Wang Jun, Synthesis and thermoresponsive behaviors of biodegradable Pluronic analogs, 10.1002/pola.23660
  16. Yapar EA, İnal Ö, Özkan Y, Baykara T, Injectable In Situ Forming Microparticles: A Novel Drug Delivery System, 10.4314/tjpr.v11i2.19
  17. Confortini Ondine, Du Prez Filip E., Functionalized Thermo-Responsive Poly(vinyl ether) by Living Cationic Random Copolymerization of Methyl Vinyl Ether and 2-Chloroethyl Vinyl Ether, 10.1002/macp.200700205
  18. Maeda Yasushi, IR Spectroscopic Study on the Hydration and the Phase Transition of Poly(vinyl methyl ether) in Water, 10.1021/la001346q
  19. Hoogenboom Richard, Poly(2-oxazoline)s: A Polymer Class with Numerous Potential Applications, 10.1002/anie.200901607
  20. Trinh Loan T. T., Lambermont-Thijs Hanneke M. L., Schubert Ulrich S., Hoogenboom Richard, Kjøniksen Anna-Lena, Thermoresponsive Poly(2-oxazoline) Block Copolymers Exhibiting Two Cloud Points: Complex Multistep Assembly Behavior, 10.1021/ma300570j
  21. Cheng He, Shen Lei, Wu Chi, LLS and FTIR Studies on the Hysteresis in Association and Dissociation of Poly(N-isopropylacrylamide) Chains in Water, 10.1021/ma052561m
  22. Schild H.G., Poly(N-isopropylacrylamide): experiment, theory and application, 10.1016/0079-6700(92)90023-r
  23. Vihola Henna, Laukkanen Antti, Valtola Lauri, Tenhu Heikki, Hirvonen Jouni, Cytotoxicity of thermosensitive polymers poly(N-isopropylacrylamide), poly(N-vinylcaprolactam) and amphiphilically modified poly(N-vinylcaprolactam), 10.1016/j.biomaterials.2004.09.008
  24. Vihola Henna, Laukkanen Antti, Tenhu Heikki, Hirvonen Jouni, Drug release characteristics of physically cross‐linked thermosensitive poly(N‐vinylcaprolactam) hydrogel particles, 10.1002/jps.21348
  25. Meeussen F., Nies E., Berghmans H., Verbrugghe S., Goethals E., Du Prez F., Phase behaviour of poly( N -vinyl caprolactam) in water, 10.1016/s0032-3861(00)00255-x
  26. Sun Shengtong, Wu Peiyi, Infrared Spectroscopic Insight into Hydration Behavior of Poly(N-vinylcaprolactam) in Water, 10.1021/jp2071056
  27. Mikheeva Larisa M., Grinberg Natalia V., Mashkevich Alexander Ya., Grinberg Valerij Ya., Thanh Le Thi Minh, Makhaeva Elena E., Khokhlov Alexei R., Microcalorimetric Study of Thermal Cooperative Transitions in Poly(N-vinylcaprolactam) Hydrogels, 10.1021/ma9615112
  28. Gao Yibing, Au-Yeung Steve C. F., Wu Chi, Interaction between Surfactant and Poly(N-vinylcaprolactam) Microgels, 10.1021/ma981756+
  29. Medeiros Simone F., Barboza Jayne C. S., Giudici Reinaldo, Santos Amilton M., Thermally-sensitive and Biocompatible Poly(N-vinylcaprolactam): A Kinetic Study of Free Radical Polymerization in Ethanol, 10.1080/10601325.2013.792662
  30. Shao Lidong, Hu Minqi, Chen Lin, Xu Li, Bi Yunmei, RAFT polymerization of N-vinylcaprolactam and effects of the end group on the thermal response of poly(N-vinylcaprolactam), 10.1016/j.reactfunctpolym.2012.04.002
  31. Beija Mariana, Marty Jean-Daniel, Destarac Mathias, Thermoresponsive poly(N-vinyl caprolactam)-coated gold nanoparticles: sharp reversible response and easy tunability, 10.1039/c0cc05184e
  32. Wan Decheng, Zhou Qing, Pu Hongting, Yang Genjin, Controlled radical polymerization ofN-vinylcaprolactam mediated by xanthate or dithiocarbamate, 10.1002/pola.22722
  33. Ponce-Vargas Sandra M., Cortez-Lemus Norma A., Licea-Claveríe Angel, Preparation of Poly(N-Vinylcaprolactam) (NVCL) and Statistical Copolymers of NVCL with Variable Cloud Point Temperature by Using A Trithiocarbonate RAFT Agent, 10.1002/masy.201200045
  34. Kermagoret Anthony, Fustin Charles-André, Bourguignon Maxime, Detrembleur Christophe, Jérôme Christine, Debuigne Antoine, One-pot controlled synthesis of double thermoresponsive N-vinylcaprolactam-based copolymers with tunable LCSTs, 10.1039/c3py00134b
  35. Liu Ji, Detrembleur Christophe, De Pauw-Gillet Marie-Claire, Mornet Stéphane, Duguet Etienne, Jérôme Christine, Gold nanorods coated with a thermo-responsive poly(ethylene glycol)-b-poly(N-vinylcaprolactam) corona as drug delivery systems for remotely near infrared-triggered release, 10.1039/c3py01057k
  36. Yu Young Chang, Li Guoxue, Kim Jinsang, Youk Ji Ho, One-pot synthesis of poly(N-vinylcaprolactam)-based biocompatible block copolymers using a dual initiator for ROP and RAFT polymerization, 10.1016/j.polymer.2013.09.013
  37. Yu Young Chang, Kang Hyun Uk, Youk Ji Ho, Synthesis and micellar characterization of thermosensitive amphiphilic poly(ε-caprolactone)-b-poly(N-vinylcaprolactam) block copolymers, 10.1007/s00396-012-2630-1
  38. Tian Wei, Lv Xiaoyan, Huang Longbiao, Ali Nazakat, Kong Jie, Multiresponsive Properties of Triple-Shell Architectures with Poly(N,N-diethylaminoethyl methacrylate), Poly(N-vinylcaprolactam), and Poly(N,N-dimethylaminoethyl methacrylate) as Building Blocks, 10.1002/macp.201200283
  39. Hurtgen Marie, Liu Ji, Debuigne Antoine, Jerome Christine, Detrembleur Christophe, Synthesis of thermo-responsive poly(N-vinylcaprolactam)-containing block copolymers by cobalt-mediated radical polymerization, 10.1002/pola.25045
  40. Liu Ji, Detrembleur Christophe, Debuigne Antoine, De Pauw-Gillet Marie-Claire, Mornet Stéphane, Vander Elst Luce, Laurent Sophie, Duguet Etienne, Jérôme Christine, Glucose-, pH- and thermo-responsive nanogels crosslinked by functional superparamagnetic maghemite nanoparticles as innovative drug delivery systems, 10.1039/c3tb21272f
  41. Liu Ji, Detrembleur Christophe, Hurtgen Marie, Debuigne Antoine, De Pauw-Gillet Marie-Claire, Mornet Stéphane, Duguet Etienne, Jérôme Christine, Reversibly crosslinked thermo- and redox-responsive nanogels for controlled drug release, 10.1039/c3py00839h
  42. Jiang Xiuyu, Li Yongjun, Lu Guolin, Huang Xiaoyu, A novel poly(N-vinylcaprolactam)-based well-defined amphiphilic graft copolymer synthesized by successive RAFT and ATRP, 10.1039/c2py20933k
  43. Jiang Xiuyu, Lu Guolin, Feng Chun, Li Yongjun, Huang Xiaoyu, Poly(acrylic acid)-graft-poly(N-vinylcaprolactam): a novel pH and thermo dual-stimuli responsive system, 10.1039/c3py00415e
  44. Nakabayashi Kazuhiro, Mori Hideharu, Recent progress in controlled radical polymerization of N-vinyl monomers, 10.1016/j.eurpolymj.2013.07.006
  45. Negru, Mater. Plast., 47, 35 (2010)
  46. Singh Pooja, Srivastava Ambika, Kumar Rajesh, Synthesis of amphiphilic poly(N-vinylcaprolactam) using ATRP protocol and antibacterial study of its silver nanocomposite, 10.1002/pola.25911
  47. Hurtgen Marie, Detrembleur Christophe, Jerome Christine, Debuigne Antoine, Insight into Organometallic-Mediated Radical Polymerization, 10.1080/15583724.2011.566401
  48. Debuigne Antoine, Poli Rinaldo, Jérôme Christine, Jérôme Robert, Detrembleur Christophe, Overview of cobalt-mediated radical polymerization: Roots, state of the art and future prospects, 10.1016/j.progpolymsci.2008.11.003
  49. Debuigne Antoine, Morin Aurélie N., Kermagoret Anthony, Piette Yasmine, Detrembleur Christophe, Jérôme Christine, Poli Rinaldo, Key Role of Intramolecular Metal Chelation and Hydrogen Bonding in the Cobalt-Mediated Radical Polymerization ofN-Vinyl Amides, 10.1002/chem.201201456
  50. Jia Yong-Guang, Zhu X. X., Complex thermoresponsive behavior of diblock polyacrylamides, 10.1039/c4py00036f
  51. Bivigou-Koumba Achille M., Kristen Juliane, Laschewsky Andre, Müller-Buschbaum Peter, Papadakis Christine M., Synthesis of Symmetrical Triblock Copolymers of Styrene andN-isopropylacrylamide Using Bifunctional Bis(trithiocarbonate)s as RAFT Agents, 10.1002/macp.200800575
  52. Ge Zhishen, Zhou Yueming, Tong Zhen, Liu Shiyong, Thermogelling of Double Hydrophilic Multiblock and Triblock Copolymers ofN,N-Dimethylacrylamide andN-Isopropylacrylamide: Chain Architectural and Hofmeister Effects, 10.1021/la1048166
  53. Skrabania Katja, Li Wen, Laschewsky André, Synthesis of Double‐Hydrophilic BAB Triblock Copolymers via RAFT Polymerisation and their Thermoresponsive Self‐Assembly in Water, 10.1002/macp.200800108
  54. Zhao Xiaoli, Liu Wenguang, Chen Dayong, Lin Xiaoze, Lu William W., Effect of Block Order of ABA- and BAB-Type NIPAAm/HEMA Triblock Copolymers on Thermoresponsive Behavior of Solutions, 10.1002/macp.200700155
  55. Kirkland Stacey E., Hensarling Ryan M., McConaughy Shawn D., Guo Yanlin, Jarrett William L., McCormick Charles L., Thermoreversible Hydrogels from RAFT-Synthesized BAB Triblock Copolymers: Steps toward Biomimetic Matrices for Tissue Regeneration†, 10.1021/bm700968t
  56. Hasan E., Zhang M., Müller A. H. E., Tsvetanov Ch. B., Thermoassociative Block Copolymers of Poly(N‐Isopropylacrylamide) and Poly(Propylene Oxide), 10.1081/ma-120030919
  57. Chen Xiangrong, Ding Xiaobin, Zheng Zhaohui, Peng Yuxing, Thermosensitive polymeric vesicles self-assembled by PNIPAAm-b-PPG-b-PNIPAAm triblock copolymers, 10.1007/s00396-004-1203-3
  58. Dai Fengying, Wang Pengfei, Wang Ying, Tang Lei, Yang Jianhai, Liu Wenguang, Li Hexian, Wang Guochang, Double thermoresponsive polybetaine-based ABA triblock copolymers with capability to condense DNA, 10.1016/j.polymer.2008.09.060
  59. Skrabania Katja, Kristen Juliane, Laschewsky André, Akdemir Özgür, Hoth Ann, Lutz Jean-François, Design, Synthesis, and Aqueous Aggregation Behavior of Nonionic Single and Multiple Thermoresponsive Polymers†, 10.1021/la061509w
  60. Debuigne Antoine, Jérôme Christine, Detrembleur Christophe, Isoprene-Assisted Radical Coupling of (Co)polymers Prepared by Cobalt-Mediated Radical Polymerization, 10.1002/anie.200804880
  61. Debuigne Antoine, Poli Rinaldo, De Winter Julien, Laurent Pascal, Gerbaux Pascal, Dubois Philippe, Wathelet Jean-Paul, Jérôme Christine, Detrembleur Christophe, Cobalt-Mediated Radical Coupling (CMRC): An Unusual Route to Midchain-Functionalized Symmetrical Macromolecules, 10.1002/chem.200902618
  62. Debuigne Antoine, Poli Rinaldo, De Winter Julien, Laurent Pascal, Gerbaux Pascal, Wathelet Jean-Paul, Jérôme Christine, Detrembleur Christophe, Effective Cobalt-Mediated Radical Coupling (CMRC) of Poly(vinyl acetate) and Poly(N-vinylpyrrolidone) (Co)polymer Precursors, 10.1021/ma902610m
  63. Debuigne Antoine, Champouret Yohan, Jérôme Robert, Poli Rinaldo, Detrembleur Christophe, Mechanistic Insights into the Cobalt-Mediated Radical Polymerization (CMRP) of Vinyl Acetate with Cobalt(III) Adducts as Initiators, 10.1002/chem.200701867
  64. Debuigne Antoine, Caille Jean-Raphaël, Jérôme Robert, Synthesis of End-Functional Poly(vinyl acetate) by Cobalt-Mediated Radical Polymerization, 10.1021/ma047726q
  65. Maeda Yasushi, Nakamura Tomoya, Ikeda Isao, Hydration and Phase Behavior of Poly(N-vinylcaprolactam) and Poly(N-vinylpyrrolidone) in Water, 10.1021/ma011034+
  66. Sokorikova, Vysokomol. Soedin., Ser. B, 27, 869 (1985)
  67. Kermagoret Anthony, Debuigne Antoine, Jérôme Christine, Detrembleur Christophe, Precision design of ethylene- and polar-monomer-based copolymers by organometallic-mediated radical polymerization, 10.1038/nchem.1850
  68. Sadeghi Rahmat, Jahani Farahnaz, Salting-In and Salting-Out of Water-Soluble Polymers in Aqueous Salt Solutions, 10.1021/jp300665b
  69. Bloksma Meta M., Bakker Daniël J., Weber Christine, Hoogenboom Richard, Schubert Ulrich S., The Effect of Hofmeister Salts on the LCST Transition of Poly(2-oxazoline)s with Varying Hydrophilicity, 10.1002/marc.200900843
  70. Hayward Ryan C., Pochan Darrin J., Tailored Assemblies of Block Copolymers in Solution: It Is All about the Process, 10.1021/ma9026806