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Nanoporous solvate of N,N-phthaloyl-glycine

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Tumanov, Nikolay [UCL] Pankrushina, N.A. Nefedov, A.A. Boldyreva, E.V.

N,N-phthaloyl-glycine is synthesized under microwave activation without solvent. Its nanoporous solvate is obtained by recrystallization. The solvate is studied by single crystal and powder XRD, thermogravimetry, and mass spectrometry. The crystals are composed of dimers that form a framework structure with infinite channels of about 4 Å in diameter, containing a non-stoichiometric amount of chloroform (the mole fraction is close to 0.35). The nature of the incorporated solvate molecules is determined by high-resolution mass spectrometry, and their quantity is found by thermogravimetry. Original Russian Text Copyright © 2012 by N. A. Tumanov, N. A. Pankrushina, A. A. Nefedov, E. V. Boldyreva.

Document type Article de périodique (Journal article) – Article de recherche
Access type Accès restreint
Publication date 2012
Language Anglais
Journal information "Journal of Structural Chemistry" - Vol. 53, no.3, p. 606-609 (2012)
Peer reviewed yes
Publisher M A I K Nauka - Interperiodica ((Russian Federation) Moscow)
issn 0022-4766
e-issn 1573-8779
Publication status Publié
Affiliation Novosibirsk State University - Solid State Chemistry
Keywords Crystal structure ; Highresolution mass spectrometry ; Nanoporous solvate of N,N-phthaloyl-glycine ; Thermogravimetry
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Bibliographic reference Tumanov, Nikolay ; Pankrushina, N.A. ; Nefedov, A.A. ; Boldyreva, E.V.. Nanoporous solvate of N,N-phthaloyl-glycine. In: Journal of Structural Chemistry, Vol. 53, no.3, p. 606-609 (2012)
Permanent URL http://hdl.handle.net/2078/154373