Thermo- and piezochromic properties of [Fe(hyptrz)]A2· H2O spin crossover 1D coordination polymer: Towards spin crossover based temperature and pressure sensors

Jureschi, C.-M. [University of Suceava (Romania)] Rusu, I. [University of Suceava (Romania)] Codjovi, E. [Université de Versailles (France)] Linares, J. [Université de Versailles (France)] Garcia, Yann [UCL] Rotaru, A. [University of Suceava (Romania)]

We have used reflectance measurements to investigate the effect of a hydrostatic pressure on the molecular 1D spin crossover coordination polymer [Fe(hyptrz)]A2·H2O (hyptrz=4-(3′- hydroxypropyl)-1,2,4-triazole and A=4-chloro-benzenesulfonate) Rev. Sci. Instrum. 80 (2009) 123901. Both thermal and pressure hysteresis have been recorded at different pressures and temperatures, respectively, in order to obtain valuable information about the optimal conditions of their use as wireless temperature and pressure sensors. The experimental analysis has been completed with a theoretical study and potential applications in terms of temperature and pressure wireless detection are discussed. © 2014 Elsevier B.V.