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From a mononuclear NiII precursor to antiferromagnetically coupled trinuclear double-stranded helicates

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Safin, D.A. [UCL] Babashkina, M.G. [UCL] Robeyns, Koen [UCL] Rouzières, M. [autre] Clérac, R. [autre] Garcia, Yann [UCL]

Reaction of the mononuclear NiII complex [Ni{2-Py(6-NH 2)NHC(S)NP(S)(OiPr)2}2] with different salicylaldehydes leads to new antiferromagnetically coupled trinuclear double-stranded helicates 1-3, where NiII metal ions are coordinated by two bis-anionic thiourea ligands and two deprotonated molecules of the corresponding aldehyde. © 2013 The Royal Society of Chemistry.

Document type Article de périodique (Journal article) – Article de recherche
Access type Accès restreint
Publication date 2013
Language Anglais
Journal information "Dalton Transactions" - Vol. 42, no.47, p. 16470-16473 (2013)
Peer reviewed yes
issn 1477-9226
Publication status Publié
Affiliation UCL - SST/IMCN/MOST - Molecules, Solids and Reactivity
Keywords Antiferro-magnetically coupled ; Double-stranded helicates ; Salicyl aldehyde ; Trinuclear ; Coordination reactions ; Metal ions ; Nickel
Links
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  13. Safin Damir A., Sokolov Felix D., Szyrwiel Łukasz, Babashkina Maria G., Gimadiev Timur R., Hahn F. Ekkehardt, Kozlowski Henryk, Krivolapov Dmitriy B., Litvinov Igor A., Nickel(II) complexes with N-(thio)phosphorylthioureas AdNHC(S)NHP(X)(OiPr)2: Versatile coordination of phosphoryl (X=O) and thiophosphoryl (X=S) derivatives, 10.1016/j.poly.2008.04.014
  14. Safin Damir A., Babashkina Maria G., Klein Axel, Sokolov Felix D., Baranov Sergey V., Pape Tania, Hahn F. Ekkehardt, Krivolapov Dmitriy B., The influence of an intramolecular hydrogen bond on the 1,3-N,S-coordination of crown ether-containing N-phosphorylthiourea with NiII, 10.1039/b9nj00252a
  15. Safin Damir A., Babashkina Maria G., Robeyns Koen, Mitoraj Mariusz P., Kubisiak Piotr, Brela Mateusz, Garcia Yann, Experimental and theoretical investigations of the NiII complex with N-phosphorylated thiourea iPrNHC(S)NHP(O)(OPh)2, 10.1039/c3ce41195h
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  17. Babashkina Maria G., Safin Damir A., Bolte Michael, Srebro Monika, Mitoraj Mariusz, Uthe André, Klein Axel, Köckerling Martin, Intramolecular hydrogen bonding controls 1,3-N,S- vs. 1,5-S,S′-coordination in NiII complexes of N-thiophosphorylated thioureas RNHC(S)NHP(S)(OiPr)2, 10.1039/c0dt01382j
  18. Babashkina Maria G., Safin Damir A., Robeyns Koen, Garcia Yann, Complexation properties of the crown ether-containing N-thiophosphorylated thiourea towards NiII, 10.1039/c1dt11958c
  19. Babashkina Maria G., Safin Damir A., Srebro Monika, Kubisiak Piotr, Mitoraj Mariusz P., Bolte Michael, Garcia Yann, Solvent-induced 1,3-N,S- vs. 1,5-S,S′-coordination in the NiII complex [Ni{p-Me2NC6H4NHC(S)NP(S)(OiPr)2}2], 10.1039/c1ce05387f
  20. Babashkina Maria G., Safin Damir A., Srebro Monika, Kubisiak Piotr, Mitoraj Mariusz P., Bolte Michael, Garcia Yann, Crucial Influence of the Intramolecular Hydrogen Bond on the Coordination Mode of RC(S)NHP(S)(OiPr)2in Homoleptic Complexes with NiII, 10.1002/ejic.201200890
  21. Babashkina Maria G., Safin Damir A., Bolte Michael, Klein Axel, Synthesis and characterization of Zn(II), Cd(II) and Ni(II) complexes with N-thiophosphorylated thioureas RC(S)NP(S)(OiPr)2 (R=MeNH, 2-MeC6H4NH, 2,6-Me2C6H3NH, 2,4,6-Me3C6H2NH, 2-Py(6-Me)NH), 10.1016/j.poly.2010.01.021
  22. Babashkina Maria G., Safin Damir A., Garcia Yann, Influence of the coordination mode in [Ni{RC(S)NP(S)(OiPr)2}2] for the formation of nickel-containing nanoparticles, 10.1039/c1dt11755f
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  26. Safin Damir A., Babashkina Maria G., Kubisiak Piotr, Mitoraj Mariusz P., Robeyns Koen, Goovaerts Etienne, Garcia Yann, Complexation properties of N-thiophosphorylated thiourea 2-PyNHC(S)NHP(S)(OiPr)2 towards NiII, 10.1039/c3dt32886d
  27. Robert François, Naik Anil D., Tinant Bernard, Robiette Raphaël, Garcia Yann, Insights into the Origin of Solid-State Photochromism and Thermochromism ofN-Salicylideneanils: The Intriguing Case of Aminopyridines, 10.1002/chem.200801932
  28. Robert François, Tinant Bernard, Clérac Rodolphe, Jacquemin Pierre-Loïc, Garcia Yann, Self assembly of asymmetric tetranuclear Cu(II) [2×2] grid-like complexes and of a dinuclear Ni(II) complex from pyridyl-phenol Schiff base ligands, 10.1016/j.poly.2010.06.017
  29. Garcia Yann, Robert François, Naik Anil D., Zhou Guangyuan, Tinant Bernard, Robeyns Koen, Michotte Sébastien, Piraux Luc, Spin Transition Charted in a Fluorophore-Tagged Thermochromic Dinuclear Iron(II) Complex, 10.1021/ja205974q
  30. Robert François, Jacquemin Pierre-Loïc, Tinant Bernard, Garcia Yann, Trans-keto* form detection in non photochromic N-salicylidene aminomethylpyridines, 10.1039/c2ce00006g
  31. Safin Damir A., Robeyns Koen, Garcia Yann, Crown ether-containing N-salicylidene aniline derivatives: synthesis, characterization and optical properties, 10.1039/c2ce25600b
  32. Safin Damir A., Robeyns Koen, Garcia Yann, Solid-state thermo- and photochromism in N,N′-bis(5-X-salicylidene)diamines (X = H, Br), 10.1039/c2ra21631k
  33. Safin Damir A., Garcia Yann, First evidence of thermo- and two-step photochromism of tris-anils, 10.1039/c3ra40705e
  34. Jacquemin Pierre-Loïc, Robeyns Koen, Devillers Michel, Garcia Yann, Reversible photochromism of an N-salicylidene aniline anion, 10.1039/c3cc45080e
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Bibliographic reference Safin, D.A. ; Babashkina, M.G. ; Robeyns, Koen ; Rouzières, M. ; Clérac, R. ; et. al. From a mononuclear NiII precursor to antiferromagnetically coupled trinuclear double-stranded helicates. In: Dalton Transactions, Vol. 42, no.47, p. 16470-16473 (2013)
Permanent URL http://hdl.handle.net/2078.1/139020