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Copper-catalyzed vinylsilane allylation

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Cornelissen, Loïc [UCL] Vercruysse, Sébastien [UCL] Sanhadji, A. [UCL] Riant, Olivier [UCL]

Soft reaction conditions, particularly important in total synthesis, have dragged many researchers into the field of silylated organic compounds. Hereby, we describe a new copper-catalyzed vinylsilane transformation. Various vinylsilanes were allylated by using a copper(I) salt, and this led to the formation of polysubstituted 1,4-dienes bearing sensitive moieties such as halogens, ketones, and aldehydes. Hereby is described a new copper-catalyzed vinylsilane transformation. Various vinylsilanes were allylated by using copper(I) salts, and this led to the formation of polysubstituted 1,4-dienes bearing sensitive moieties such as halogens, ketones, and aldehydes. TBAT = tetrabutylammonium difluorotriphenylsilicate. Copyright © 2014 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

Document type Article de périodique (Journal article) – Article de recherche
Access type Accès restreint
Publication date 2014
Language Anglais
Journal information "European Journal of Organic Chemistry" - Vol. 2014, no.1, p. 35-38 (2014)
Peer reviewed yes
issn 1434-193X
Publication status Publié
Affiliation UCL - SST/IMCN/MOST - Molecules, Solids and Reactivity
Keywords Allylation ; Copper ; Cross-coupling ; Silicon ; Vinylsilanes
Links
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Bibliographic reference Cornelissen, Loïc ; Vercruysse, Sébastien ; Sanhadji, A. ; Riant, Olivier. Copper-catalyzed vinylsilane allylation. In: European Journal of Organic Chemistry, Vol. 2014, no.1, p. 35-38 (2014)
Permanent URL http://hdl.handle.net/2078.1/137170