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Polyelectrolyte Complex Nanoparticles from Chitosan and Poly(acrylicacid) and Polystyrene-block-Poly(acrylic acid)

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Rolland, Julien [UCL] Guillet, Pierre [UCL] Schumers, Jean-Marc [UCL] Duhem, Nicolas [UCL] Préat, Véronique [UCL] Gohy, Jean-François [UCL]

Interpolymer polyelectrolyte complexes of chitosan (CS) with poly(acrylic acid) homopolymers and polystyreneblock- poly(acrylic acid) diblock copolymers were prepared and characterized. The influence of the positive/negative charge balance (charge ratio), pH, and ionic strength were thoroughly studied by dynamic light scattering. The existence of a strong polyelectrolyte effect was also highlighted in this study. Domains of stability, in which nanoparticle sizes are smaller than 100 and 200 nm for complexes of CS with the homopolymer and copolymer, respectively, were identified and confirmed by scanning electron microscopy and atomic force microscopy. The charged nature of the surface of the nanoparticles was evidenced by Zeta potential measurements

Document type Article de périodique (Journal article) – Article de recherche
Access type Accès interdit
Publication date 2012
Language Anglais
Journal information "Journal of Polymer Science. Part A, Polymer Chemistry" - Vol. 50, no.21, p. 4484–4493 (November 2012)
Peer reviewed yes
Publisher JohnWiley & Sons, Inc. ((United States) Hoboken)
issn 0887-624X
e-issn 1099-0518
Publication status Publié
Affiliation UCL - SST/IMCN/BSMA - Bio and soft matter
Keywords biopolymers ; chitosan ; dynamic light scattering ; nanoparticles ; polyelectrolytes
Links
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Bibliographic reference Rolland, Julien ; Guillet, Pierre ; Schumers, Jean-Marc ; Duhem, Nicolas ; Préat, Véronique ; et. al. Polyelectrolyte Complex Nanoparticles from Chitosan and Poly(acrylicacid) and Polystyrene-block-Poly(acrylic acid). In: Journal of Polymer Science. Part A, Polymer Chemistry, Vol. 50, no.21, p. 4484–4493 (November 2012)
Permanent URL http://hdl.handle.net/2078.1/128657