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Ligand assisted cleavage of uranium oxo-clusters

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Nocton, G. Pécaut, J. Filinchuk, Yaroslav [UCL] Mazzanti, M.

Dibenzoylmethanate replaces the bridging triflate ligands in uranium triflate polyoxo-clusters and cleaves the U12O20 core yielding the new [U6O4(OH)4(η-dbm) 12] dibenzoylmethanate (dbm-) cluster which slowly dissociates into a monomeric complex. This reactivity demonstrates the importance of bridging ligands in stabilizing uranium polyoxo-clusters. © 2010 The Royal Society of Chemistry.

Document type Article de périodique (Journal article) – Article de recherche
Publication date 2010
Language Anglais
Journal information "Chemical Communications" - Vol. 46, no.16, p. 2757-2759 (2010)
Peer reviewed yes
issn 1359-7345
Publication status Publié
Affiliation ESRF, Grenoble (France) - Chimie
Keywords Dibenzoylmethanate ; Thermal analysis ; Ligand ; Methane ; Unclassified drug ; Uranium ; Article ; Chemical reaction ; Cluster analysis ; Temperature dependence
Links
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Bibliographic reference Nocton, G. ; Pécaut, J. ; Filinchuk, Yaroslav ; Mazzanti, M.. Ligand assisted cleavage of uranium oxo-clusters . In: Chemical Communications, Vol. 46, no.16, p. 2757-2759 (2010)
Permanent URL http://hdl.handle.net/2078/126874