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Pressure and temperature spin crossover sensors with optical detection

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Linares, J. [Université de Versailles (France)] Codjovi, E. [Université de Versailles (France)] Garcia, Yann [UCL]

Iron(II) spin crossover molecular materials are made of coordination centres switchable between two states by temperature, pressure or a visible light irradiation. The relevant macroscopic parameter which monitors the magnetic state of a given solid is the high-spin (HS) fraction denoted nHS, i.e., the relative population of HS molecules. Each spin crossover material is distinguished by a transition temperature T1/2 where 50% of active molecules have switched to the low-spin (LS) state. In strongly interacting systems, the thermal spin switching occurs abruptly at T1/2. Applying pressure induces a shift from HS to LS states, which is the direct consequence of the lower volume for the LS molecule. Each material has thus a well defined pressure value P1/2. In both cases the spin state change is easily detectable by optical means thanks to a thermo/piezochromic effect that is often encountered in these materials. In this contribution, we discuss potential use of spin crossover molecular materials as temperature and pressure sensors with optical detection. The ones presenting smooth transitions behaviour, which have not been seriously considered for any application, are spotlighted as potential sensors which should stimulate a large interest on this well investigated class of materials. © 2012 by the authors; licensee MDPI, Basel, Switzerland.

Document type Article de périodique (Journal article) – Article de recherche
Access type Accès libre
Publication date 2012
Language Anglais
Journal information "Sensors" - Vol. 12, no.4, p. 4479-4492 (2012)
Peer reviewed yes
issn 1424-8220
Publication status Publié
Affiliation UCL - SST/IMCN/MOST - Molecules, Solids and Reactivity
Keywords Optical detection ; Pressure sensors ; Sensitive paints ; Smart materials ; Spin crossover
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Bibliographic reference Linares, J. ; Codjovi, E. ; Garcia, Yann. Pressure and temperature spin crossover sensors with optical detection . In: Sensors, Vol. 12, no.4, p. 4479-4492 (2012)
Permanent URL http://hdl.handle.net/2078.1/125493