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Influence of the coordination mode in [Ni{RC(S)NP(S)(OiPr)2)2] for the formation of nickel-containing nanoparticles

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Babashkina, M.G. [UCL] Safin, Damir [UCL] Garcia, Yann [UCL]

The complex [Ni{2-PyNHC(S)NP(S)(OiPr) 2-1,5,7-N,N′,S} 2] ([NiL I 2]) dissolved in tri-n-octylphosphine (TOP) is decomposed in hot hexadecylamine (HDA) to give TOP-capped Ni nanoparticles. The same procedure using [Ni{2-MeC 6H 4NHC(S)NP(S)(OiPr) 2} 2-1,3-N,S] ([NiL II 2]) and [Ni{PhC(S)NP(S)(OiPr) 2-1,5-S, S′} 2] ([NiL III 2]) leads to the formation of NiS nanoparticles with the rhombohedral and hexagonal structures, respectively. NiH x nanoparticles were also produced from a mixture of [NiL I 2] and N 2H 4. The obtained Ni nanoparticles can be used for the catalytic addition of Ph 2S 2 to 1-, 2- and 3-hexynes. © The Royal Society of Chemistry 2012.

Document type Article de périodique (Journal article) – Article de recherche
Access type Accès restreint
Publication date 2012
Language Anglais
Journal information "Dalton Transactions" - Vol. 41, no.8, p. 2234-2236 (2012)
Peer reviewed yes
Publisher The Royal Society of Chemistry
issn 1477-9226
Publication status Publié
Affiliation UCL - SST/IMCN/MOST - Molecules, Solids and Reactivity
Keywords Catalytic addition ; Coordination modes ; Hexadecylamine ; Hexagonal structures ; Ni Nanoparticles ; Tri-n-octylphosphine ; Coordination reactions ; Nanoparticles
Links
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Bibliographic reference Babashkina, M.G. ; Safin, Damir ; Garcia, Yann. Influence of the coordination mode in [Ni{RC(S)NP(S)(OiPr)2)2] for the formation of nickel-containing nanoparticles . In: Dalton Transactions, Vol. 41, no.8, p. 2234-2236 (2012)
Permanent URL http://hdl.handle.net/2078.1/125489