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Radical addition of xanthates on carbon nanotubes as an efficient covalent functionalization method

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Vanhorenbeke, Béatrice [UCL] Vriamont, Charles [UCL] Pennetreau, Florence [UCL] Devillers, Michel [UCL] Riant, Olivier [UCL] Hermans, Sophie [UCL]

Radical-initiated support: Xanthates were used as chemical reagents for the sidewall covalent functionalization of carbon nanotubes (see figure). The best grafting yields were obtained with stoichiometric ratios of xanthate and the radical initiator lauroyl peroxide. One grafted function was used as a tether for bimetallic cluster compounds, which were converted into very small (1-2nm) supported nanoparticles upon heating. Copyright © 2013 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

Document type Article de périodique (Journal article) – Article de recherche
Access type Accès restreint
Publication date 2013
Language Anglais
Journal information "Chemistry: A European Journal" - Vol. 19, no. 3, p. 852-856 (2013)
Peer reviewed yes
Publisher Wiley - V C H Verlag GmbH & Co. KGaA ((Germany) Weinheim)
issn 0947-6539
e-issn 1521-3765
Publication status Publié
Affiliation UCL - SST/IMCN/MOST - Molecules, Solids and Reactivity
Keywords Cluster compounds ; Covalent functionalizations ; Grafting yield ; Radical addition ; Radical initiators ; Radicals ; Stoichiometric ratio ; Supported nanoparticles ; Xanthate ; Carbon nanotubes ; Grafting (chemical) ; Covalent functionalization ; Nanoparticles ; Nanotubes ; Vinyl resins ; Nanoparticles ; Nanotubes ; Radicals ; Xanthate ; Bimetallic clusters ; Chemical reagents ; Cluster compounds
Links
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Bibliographic reference Vanhorenbeke, Béatrice ; Vriamont, Charles ; Pennetreau, Florence ; Devillers, Michel ; Riant, Olivier ; et. al. Radical addition of xanthates on carbon nanotubes as an efficient covalent functionalization method. In: Chemistry: A European Journal, Vol. 19, no. 3, p. 852-856 (2013)
Permanent URL http://hdl.handle.net/2078.1/125263