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A metal-organic framework made of an asymmetric 1,2,4-triazole and tetrazole ligand

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Boland, Yves [UCL] Tinant, Bernard [UCL] Safin, Damir [UCL] Marchand-Brynaert, Jacqueline [UCL] Clérac, R. [Université de Bordeaux (France)] Garcia, Yann [UCL]

Reaction of the asymmetric ligand, 1-[3′-(1,2,4-triazol-4-yl)propyl] tetrazole (L) with Cu(BF 4) 2 in water leads to the Cu II metal-organic framework [CuL(OH)]BF 4 (I). According to X-ray analysis, L connects four Cu II ions, where the 1,2,4-triazole and tetrazole units exhibit a bridging bis-monodentate μ 2-N1,N2 and a unique μ 2-N2,N3 coordination modes, respectively. © 2012 The Royal Society of Chemistry.

Document type Article de périodique (Journal article) – Article de recherche
Access type Accès restreint
Publication date 2012
Language Anglais
Journal information "CrystEngComm" - Vol. 14, no.23, p. 8153-8155 (2012)
Peer reviewed yes
Publisher RSC
issn 1466-8033
Publication status Publié
Affiliation UCL - SST/IMCN/MOST - Molecules, Solids and Reactivity
Links
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Bibliographic reference Boland, Yves ; Tinant, Bernard ; Safin, Damir ; Marchand-Brynaert, Jacqueline ; Clérac, R. ; et. al. A metal-organic framework made of an asymmetric 1,2,4-triazole and tetrazole ligand. In: CrystEngComm, Vol. 14, no.23, p. 8153-8155 (2012)
Permanent URL http://hdl.handle.net/2078.1/124614