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Rotaxane-based mechanically linked block copolymers

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De Bo, Guillaume De Winter, Julien Gerbaux, Pascal Fustin, Charles-André [UCL]

We just clicked: A convergent approach consisting of two successive copper(I)-catalyzed azide-alkyne cycloaddition "click" reactions leads to a diblock copolymer in which the two blocks are linked by a rotaxane-type mechanical bond (see scheme). Rotaxane formation is templated by a square-planar PdII complex. Copyright © 2011 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

Document type Article de périodique (Journal article) – Article de recherche
Access type Accès restreint
Publication date 2011
Language Anglais
Journal information "Angewandte Chemie - International Edition" - Vol. 50, no. 39, p. 9093-9096 (2011)
Peer reviewed yes
issn 1433-7851
Publication status Publié
Affiliation UCL - SST/IMCN/BSMA - Bio and soft matter
Keywords Block copolymers ; Click chemistry ; Rotaxanes ; Templated ; Acetylene ; Block copolymers ; Palladium compounds ; Supramolecular chemistry ; Palladium ; Palladium ; Rotaxanes ; Supramolecular chemistry ; Azide-alkyne cycloaddition ; Click chemistry ; Convergent approach ; Diblock copolymer ; Mechanical bonds
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Bibliographic reference De Bo, Guillaume ; De Winter, Julien ; Gerbaux, Pascal ; Fustin, Charles-André. Rotaxane-based mechanically linked block copolymers. In: Angewandte Chemie - International Edition, Vol. 50, no. 39, p. 9093-9096 (2011)
Permanent URL http://hdl.handle.net/2078.1/108173