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A three-component tandem reductive aldol reaction catalyzed by N-heterocyclic carbene-copper complexes.

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Welle, Alexandre [UCL] Díez-González, Silvia Tinant, Bernard [UCL] Nolan, Steven P Riant, Olivier [UCL]

[Structure: see text] An efficient catalytic system for the three-component coupling of electrophilic alkenes, aldehydes, and silane was optimized with a new family of copper N-heterocyclic carbene complexes. These catalysts do not require activation and show high activity (TOF>15,000 h-1) as well as some anti diastereoselectivity.

Document type Article de périodique (Journal article) – Journal Article, Research Support, Non-U.S. Gov't
Access type Accès restreint
Publication date 2006
Journal information "Organic letters" - Vol. 8, no. 26, p. 6059-62 (2006)
Peer reviewed yes
issn 1523-7060
Publication status Publié
Affiliation UCL - SC/CHIM - Département de chimie
MESH Subject Catalysis ; Copper - chemistry ; Heterocyclic Compounds - chemistry ; Hydrocarbons - chemistry ; Methane - analogs & derivatives - chemistry ; Models, Molecular ; Oxidation-Reduction
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Bibliographic reference Welle, Alexandre ; Díez-González, Silvia ; Tinant, Bernard ; Nolan, Steven P ; Riant, Olivier. A three-component tandem reductive aldol reaction catalyzed by N-heterocyclic carbene-copper complexes.. In: Organic letters, Vol. 8, no. 26, p. 6059-62 (2006)
Permanent URL http://hdl.handle.net/2078.1/10799