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Simple and Efficient Preparation of Dihydropyrans and Spiroketals Using the Intramolecular Silyl Modified Sakurai (isms) Reaction

Onglets principaux

Marko, Istvan [UCL] Bayston, DJ. Mekhalfia, A. Adams, H.

Substituted tetrahydropyrans, spiroethers and spiroketals can be prepared in a single step using the ISMS reaction between the bis-silylated reagent 7b and aldehydes (acetals), ketones (ketals) and ortholactones respectively. This simple methodology was applied to the rapid synthesis of a pheromone containing a [4,5]-spiroketal unit.

Type de document Article de périodique (Journal article) – Article de recherche
Année de publication 1993
Langue Anglais
Information sur le périodique "Societes Chimiques Belges. Bulletin" - Vol. 102, no. 10, p. 655-661 (1993)
Peer reviewed oui
Editeur Soc Chimique Belgique (Brussels)
issn 0037-9646
Statut de la publication Publié
Affiliations UCL
Liens
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Référence bibliographique Marko, Istvan ; Bayston, DJ. ; Mekhalfia, A. ; Adams, H.. Simple and Efficient Preparation of Dihydropyrans and Spiroketals Using the Intramolecular Silyl Modified Sakurai (isms) Reaction. In: Societes Chimiques Belges. Bulletin, Vol. 102, no. 10, p. 655-661 (1993)
Permalien http://hdl.handle.net/2078.1/49089