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Crystal structure and physical properties of the new linear chain compound [Cu(1,2-bis(tetrazol-1-yl)ethane)3](ClO4)2

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van Koningsbruggen, Petra J. Garcia, Yann [UCL] Bravic, Georges Chasseau, Daniel Kahn, Olivier

The synthesis and crystal structure of a novel one-dimensional Cu(II) compound [Cu(1,2-bis(tetrazol-1-yl)ethane)3](ClO4)2 are described. The single-crystal X-ray structure determination was carried out at 298 K. The molecular structure consists of a linear chain in which the Cu(II) ions are linked by three N4,N4' coordinating bis(tetrazole) ligands in syn conformation. The Cu(II) ions are in a Jahn–Teller distorted octahedral environment (Cu(1)-N(11)=2.034(2) A- , Cu(1)-N(21)=2.041(2) A- and Cu(1)-N(31)= 2.391(2) A- ). The Cu···Cu separations are 7.420(3) A.

Document type Article de périodique (Journal article)
Access type Accès restreint
Publication date 2001
Language Anglais
Journal information "Inorganica Chimica Acta" - Vol. 326, no. 1, p. 101-105 (2001)
Peer reviewed yes
Publisher Elsevier BV ((Netherlands) Amsterdam)
issn 0020-1693
e-issn 1873-3255
Publication status Publié
Affiliation University of Mainz (Germany) - Inorganic and Analytical Chemistry
Links
Bibliographic reference van Koningsbruggen, Petra J. ; Garcia, Yann ; Bravic, Georges ; Chasseau, Daniel ; Kahn, Olivier. Crystal structure and physical properties of the new linear chain compound [Cu(1,2-bis(tetrazol-1-yl)ethane)3](ClO4)2. In: Inorganica Chimica Acta, Vol. 326, no. 1, p. 101-105 (2001)
Permanent URL http://hdl.handle.net/2078/92610