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Studies towards the Synthesis of Pentalenene: Mechanistic Insights into the Isomerization Phenomenon During RCM of Medium-Sized Rings

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De Bo, Guillaume [UCL] Marko, Istvan [UCL]

Isomerization issues have been encountered during the ring-closing metathesis (RCM) step of a new approach towards pentalenene. This paper describes the mechanistic insights gained during the study of this side reaction from a substrate perspective. Isomerization issues have been encountered during the RCM step of a new approach towards pentalenene.

Document type Article de périodique (Journal article) – Article de recherche
Access type Accès restreint
Publication date 2011
Language Anglais
Journal information "European Journal of Organic Chemistry" - Vol. 2011, no. 10, p. 1859-1869 (25 february 2011)
Peer reviewed yes
Publisher Wiley - V C H Verlag GmbH & Co. KGaA ((Germany) Weinheim)
issn 1434-193X
e-issn 1099-0690
Publication status Publié
Affiliation UCL - SST/IMCN/MOST - Molecules, Solids and Reactivity
Keywords Ring-closing metathesis ; Medium-ring compounds ; Isomerization ; Ruthenium ; 1313
Links
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Bibliographic reference De Bo, Guillaume ; Marko, Istvan. Studies towards the Synthesis of Pentalenene: Mechanistic Insights into the Isomerization Phenomenon During RCM of Medium-Sized Rings. In: European Journal of Organic Chemistry, Vol. 2011, no. 10, p. 1859-1869 (25 february 2011)
Permanent URL http://hdl.handle.net/2078.1/90512