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Upper Critical Solution Temperature Switchable Micelles Based on Polystyrene-block-poly(methyl acrylate) Block Copolymers

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Can, Aydin [] Hoeppener, Stephanie [] Guillet, Pierre [] Gohy, Jean-François [UCL] Hoogenboom, Richard [] Schubert, Ulrich S. []

The solubility behavior of well-defined poly(methyl acrylate) homopolymers as well as polystyrene-block-poly (methylacrylate) block copolymers is discussed in this contribution. A solubility screening in ethanol-water solvent mixtures was performed in a high-throughput manner using parallel turbidimetry revealing upper critical solution temperature behavior for poly(methyl acrylate). Moreover, the self-assembly behavior of the block copolymers into micellar structures was investigated by dynamic light scattering (DLS), transmission electron microscopy (TEM), and cryo-TEM revealing upper critical solution temperature switchability of the micelles, which was evaluated by DLS at different temperatures. (C) 2011 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 49: 3681-3687, 2011

Document type Article de périodique (Journal article) – Article de recherche
Access type Accès restreint
Publication date 2011
Language Anglais
Journal information "Journal of polymer science part a-polymer chemistry" - Vol. 49, no. 17, p. 3681-3687 (2011)
Peer reviewed yes
issn 0887-624X
Publication status Publié
Affiliation UCL - SST/IMCN/BSMA - Bio and soft matter
Links
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Bibliographic reference Can, Aydin ; Hoeppener, Stephanie ; Guillet, Pierre ; Gohy, Jean-François ; Hoogenboom, Richard ; et. al. Upper Critical Solution Temperature Switchable Micelles Based on Polystyrene-block-poly(methyl acrylate) Block Copolymers . In: Journal of polymer science part a-polymer chemistry, Vol. 49, no. 17, p. 3681-3687 (2011)
Permanent URL http://hdl.handle.net/2078.1/90122