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Efficient enantioselective hydrosilylation of ketones catalyzed by air stable copper fluoride-phosphine complexes.

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Sirol, S Courmarcel, J Mostefai, Naouël [UCL] Riant, Olivier [UCL]

[reaction: see text] Copper(II) fluoride-chiral diphosphine systems catalyze the hydrosilylation of several ketones with moderate to excellent enantioselectivities. An oxygen acceleration effect was observed and led to a practical protocol with low catalyst loading.

Document type Article de périodique (Journal article) – Journal Article
Access type Accès restreint
Publication date 2001
Journal information "Organic letters" - Vol. 3, no. 25, p. 4111-3 (2001)
Peer reviewed yes
issn 1523-7060
Publication status Publié
Affiliation UCL - SC/CHIM - Département de chimie
Links
Bibliographic reference Sirol, S ; Courmarcel, J ; Mostefai, Naouël ; Riant, Olivier. Efficient enantioselective hydrosilylation of ketones catalyzed by air stable copper fluoride-phosphine complexes.. In: Organic letters, Vol. 3, no. 25, p. 4111-3 (2001)
Permanent URL http://hdl.handle.net/2078.1/9006