Hybrid synthesis and processing schemes for highly-ordered polyaniline nanoarchitectures.

Vlad, Alexandru [UCL] Jedrasik, P. [Chalmers University of Technology, Sweden] Dutu, Constantin Augustin [UCL] Serban, Dana Alina [UCL] Guillet, Pierre [UCL] Fustin, Charles-André [UCL] Södervall, U. [Chalmers University of Technology, Sweden] Gohy, Jean-François [UCL] Melinte, Sorin [UCL] et al.[show all]

We report on a newly developed technology for the nanoscale processing of the conducting polyaniline (PANI) with an unprecedented areal patterning order and density control exceeding 0.25 teradot/inch/sup 2/. A simple two-step process is put forward to hierarchically build a large variety of functional PANI nanostructures on virtually any type of flexible or rigid substrates. Using template confinement, through Pt catalyzed electroless growth, highly-ordered arrays of distinct PANI nanowires are produced. Complex three-dimensional (3D) structural control is achieved through a direct pattern transfer using a novel type of resist- and dose-modulated 3D electron beam lithography. The method is scalable and provides a generic approach for nanopatterning surfaces with functional polymers. Aspects of the nanoscale PANI growth mechanism are discussed and the highly controllable, sub-picogram scale fabrication is emphasized. Simple schemes for single PANI nanowire fabrication, processing and device integration are presented.