Fayt, André
[UCL]
Van Lerberghe, D.
Kupfer, J.P.
Pascher, H.
Hafele, H.G.
With the use of a conventional high-resolution grating spectrometer and a Q-switched spin-flip Raman laser (SFRL), carbonyl sulphide ro-vibrational bands between 1852 and 1914 cm/sup -1/ have been measured and analysed. Rotational constants for seven bands have been calculated, including bands of the two isotopic species O/sup 13 /CS and OC/sup 34/S occurring in natural abundance. The 12/sup 0/0 larr 00/sup 0/0 band of OCS has been measured with an absolute accuracy of 0.002 cm/sup -1/ and so can be used for the calibration of the SFRL spectra in the 5.3 mu m region.
Bibliographic reference |
Fayt, André ; Van Lerberghe, D. ; Kupfer, J.P. ; Pascher, H. ; Hafele, H.G.. Analysis of vibration-rotation bands of OCS in the 5.3 mu m region using a tunable Q-switched spin-flip Raman laser. In: Molecular Physics : an international journal at the interface between chemistry and physics, Vol. 33, no. 3, p. 603-610 (1977) |
Permanent URL |
http://hdl.handle.net/2078.1/66655 |