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Selective Hydrogenation of 3 Butenonitrile and 2 Butenonitrile On Palladium Exchanged Titanium Pillared Montmorillonite

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Lamesch, A. Delcastillo, H. Vanderwegen, P. Daza, L. Jannes, G. Grange, Paul [UCL]

Thermally stable titanium pillared montmorillonite have been synthesized and used as support for preparing palladium exchanged high microporous catalysts. Low Pd content does not modify the physico-chemical properties of the pillared support, while 3 wt% Pd deposited on the Ti montmorillonite slightly decreases the surface area and microporosity of the catalysts. Selective hydrogenation of 3 butenonitrile and 2 butenonitrile to butyronitrile is observed without isomerization. Progressive poisoning of the catalytic sites and possible diffusional limitations alter the activity of these catalysts.

Document type Communication à un colloque (Conference Paper) – Présentation orale avec comité de sélection
Publication date 1993
Language Anglais
Conference "3rd International Symposium on Heterogeneous Catalysis and Fine Chemicals", POITIERS(France) (Apr 05-08, 1993)
Journal information "Studies in Surface Science and Catalysis" - Vol. 78, p. 299-304 (1993)
Peer reviewed yes
issn 0167-2991
Publisher Elsevier Science Publ B V (Amsterdam)
Affiliation UCL - Autre
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Bibliographic reference Lamesch, A. ; Delcastillo, H. ; Vanderwegen, P. ; Daza, L. ; Jannes, G. ; et. al. Selective Hydrogenation of 3 Butenonitrile and 2 Butenonitrile On Palladium Exchanged Titanium Pillared Montmorillonite.3rd International Symposium on Heterogeneous Catalysis and Fine Chemicals (POITIERS(France), Apr 05-08, 1993). In: Studies in Surface Science and Catalysis, Vol. 78, p. 299-304 (1993)
Permanent URL http://hdl.handle.net/2078.1/63286