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Radiation-chemistry of N-hexane Aqueous-solutions As Studies By Chromatographic Analysis of Final Products

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Dedoncker, J. Tilquin, Bernard [UCL]

Radiolysis of dilute oxygen-free hexane aqueous solutions give dodecanes isomers analyzed by capillary gas chromatography. The relative yields for radicals which react by radical-radical recombination reactions are 39 %, 32 % and 29 % for primary hexyl radical, secondary-2 hexyl radical and secondary-3 hexyl radical respectively. This distribution is changed with the N2O saturation before the radiolysis to 22 %, 42 % and 37 %. If the first distribution is statistic, the increase of OH available to attack the solute gives the distribution existing in pure alkane radiolysis.

Document type Article de périodique (Journal article) – Article de recherche
Publication date 1991
Language Anglais
Journal information "Societes Chimiques Belges. Bulletin" - Vol. 100, no. 2, p. 107-113 (1991)
Peer reviewed yes
Publisher Soc Chimique Belgique (Brussels)
issn 0037-9646
Publication status Publié
Affiliation UCL - MD/FARM - Ecole de pharmacie
Links
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Bibliographic reference Dedoncker, J. ; Tilquin, Bernard. Radiation-chemistry of N-hexane Aqueous-solutions As Studies By Chromatographic Analysis of Final Products. In: Societes Chimiques Belges. Bulletin, Vol. 100, no. 2, p. 107-113 (1991)
Permanent URL http://hdl.handle.net/2078.1/51233