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Ene-type Addition of Alkenes To Phenyl Vinylsulfoxide

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Brichard, MH. Janousek, Z. Merenyi, R. Viehe, HG.

Phenyl vinylsulfoxide reacts under acylating conditions (TFA, TFAA) with isobutene to give double 'ene" alpha,beta-adduct Propene and other alkenes examined afford a beta-"ene" alkylation accompanied by trifluoroacetoxylation at the same carbon atom.

Document type Article de périodique (Journal article) – Article de recherche
Access type Accès restreint
Publication date 1992
Language Anglais
Journal information "Tetrahedron Letters" - Vol. 33, no. 18, p. 2511-2514 (1992)
Peer reviewed yes
Publisher Pergamon-elsevier Science Ltd (Oxford)
issn 0040-4039
e-issn 1873-3581
Publication status Publié
Affiliation UCL
Keywords ENE REACTION ; VINYLSULFOXIDE ; ALKYLATION ; TRIFLUOROACETOXYLATION ; EPISULFONIUM CATION
Links
Bibliographic reference Brichard, MH. ; Janousek, Z. ; Merenyi, R. ; Viehe, HG.. Ene-type Addition of Alkenes To Phenyl Vinylsulfoxide. In: Tetrahedron Letters, Vol. 33, no. 18, p. 2511-2514 (1992)
Permanent URL http://hdl.handle.net/2078.1/50431