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Stereochemistry of the Carroll Rearrangement - Structure of (+)-(2r)-2-[(1r,5r)-5-methyl-2-oxocyclopentyl]-propionic Acid, C9h14o3

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Ouvrard, N. Declercq, Jean-Paul [UCL] Baldy, A. Rodriguez, J. Santelli, M. Feneaudupont, J.

The configurations at the three chiral centres are R, R and R. The two substituents of the almost planar cyclopentanone are trans and the C2-C6-C10-C11 torsion angle is - 79 (1)-degrees.

Document type Article de périodique (Journal article) – Article de recherche
Publication date 1994
Language Anglais
Journal information "Acta Crystallographica. Section C: Crystal Structure Communications" - Vol. 50, p. 624-625 (1994)
Peer reviewed yes
Publisher Munksgaard Int Publ Ltd (Copenhagen)
issn 0108-2701
e-issn 1600-5759
Publication status Publié
Affiliation UCL
Links
Bibliographic reference Ouvrard, N. ; Declercq, Jean-Paul ; Baldy, A. ; Rodriguez, J. ; Santelli, M. ; et. al. Stereochemistry of the Carroll Rearrangement - Structure of (+)-(2r)-2-[(1r,5r)-5-methyl-2-oxocyclopentyl]-propionic Acid, C9h14o3. In: Acta Crystallographica. Section C: Crystal Structure Communications, Vol. 50, p. 624-625 (1994)
Permanent URL http://hdl.handle.net/2078.1/48994