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Synthesis of Conjugated Dienes From Propene Or Other Alkenes By the Ene-type Reaction of Thionium Ions

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Schmitz, C. Harvey, JN. Viehe, HG.

The known ene-type addition of thionium ions to alkenes has now been applied to the synthesis of homoallylic sulfides, from thionium ions RHC = S+Ar (R = alkyl, Ar = 4-chlorophenyl) and propene or other unactivated alkenes. Oxidation and thermal dehydrosulfenylation then lead to conjugated dienes. Because the reaction conditions are compatible with many functional groups, this method is simple and useful.

Document type Article de périodique (Journal article) – Article de recherche
Publication date 1994
Language Anglais
Journal information "Societes Chimiques Belges. Bulletin" - Vol. 103, no. 3, p. 105-114 (1994)
Peer reviewed yes
Publisher Soc Chimique Belgique (Brussels)
issn 0037-9646
Publication status Publié
Affiliation UCL
Links
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Bibliographic reference Schmitz, C. ; Harvey, JN. ; Viehe, HG.. Synthesis of Conjugated Dienes From Propene Or Other Alkenes By the Ene-type Reaction of Thionium Ions. In: Societes Chimiques Belges. Bulletin, Vol. 103, no. 3, p. 105-114 (1994)
Permanent URL http://hdl.handle.net/2078.1/48824