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3-thio-claisen Rearrangement of the Allyl Vinyl Sulfonium Ion

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Harvey, JN. Viehe, HG.

Generated in situ, the parent allyl vinyl sulfonium ion rapidly undergoes the title rearrangement to give a gamma,delta-unsaturated thionium ion; a similar process appears to be involved in the reaction of phenyl vinyl sulfoxide with isobutene.

Document type Article de périodique (Journal article) – Article de recherche
Publication date 1995
Language Anglais
Journal information "Chemical Society. Journal. Chemical Communications" - , no. 22, p. 2345-2346 (1995)
Peer reviewed yes
Publisher Royal Soc Chemistry (Cambridge)
issn 0022-4936
Publication status Publié
Affiliation UCL
Links
Bibliographic reference Harvey, JN. ; Viehe, HG.. 3-thio-claisen Rearrangement of the Allyl Vinyl Sulfonium Ion. In: Chemical Society. Journal. Chemical Communications, , no. 22, p. 2345-2346 (1995)
Permanent URL http://hdl.handle.net/2078.1/47693