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Organotin phosphinates and arseniates R(2)SnA(2), R2Sn(Cl)A, Me3Sn(O2PPh2) (R = Me, Bu; A = Me2AsO2, Ph2PO2): Synthesis, IR, Raman, Mossbauer and NMR studies

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Sidibe, M Lahlou, M Diop, L Mahieu, Bernard [UCL]

Derivatives of general formulae R(2)SnA(2), R2Sn(Cl)A and Me3Sn(O2PPh2) (R = Me, Bu; A = Me2AsO2, Ph2PO2) have been synthesized and their elemental analyses performed. From the spectroscopic data (i. r., Raman, Mossbauer and NMR) polymeric structures containing symmetrically or unsymmetrically octahedral trans coordinated SnR2 residue and an infinite chain with a trigonal bipyramidal environment around the tin center for Me3Sn(O2PPh2) have been suggested.

Document type Article de périodique (Journal article) – Article de recherche
Publication date 1998
Language Anglais
Journal information "Silicon, Germanium, Tin and Lead Compounds" - Vol. 21, no. 10, p. 605-608 (1998)
Peer reviewed yes
Publisher Freund Publishing House Ltd (London)
issn 0334-7575
Publication status Publié
Affiliation UCL
Links
Bibliographic reference Sidibe, M ; Lahlou, M ; Diop, L ; Mahieu, Bernard. Organotin phosphinates and arseniates R(2)SnA(2), R2Sn(Cl)A, Me3Sn(O2PPh2) (R = Me, Bu; A = Me2AsO2, Ph2PO2): Synthesis, IR, Raman, Mossbauer and NMR studies. In: Silicon, Germanium, Tin and Lead Compounds, Vol. 21, no. 10, p. 605-608 (1998)
Permanent URL http://hdl.handle.net/2078.1/45000