Terrones, Mauricio
[UCL]
Charlier, Jean-Christophe
[UCL]
Banhart, F.
Grobert, N.
Terrones, Humberto
[UCL]
Ajayan, P.M.
Using state-of-the-art electron microscopy, we demonstrate that high-energy electron irradiation at elevated temperatures (700-800degreesC) results in the molecular merging of adjacent single-walled carbon nanotubes (SWNTs) via a zipper-like mechanism. In order to elucidate this coalescence process, we perform tight-binding molecular dynamics (TBMD) calculations at 1000degreesC. These simulations indicate that only a few vacancies (generated experimentally by knock-on effects on the tube surfaces) between two adjacent tubes of the same chirality trigger tube coalescence via a zipper-like mechanism. We further demonstrate theoretically that two crossing tubes containing a limited number of vacancies (dangling bonds) connect molecularly at 1000degreesC, resulting in the creation of an "X" molecular nanotube junction. Along this line, we propose a method for creating novel nanotube "X" and "Y" junctions, which could be developed in the fabrication of nanotube heterojunctions, robust composites, contacts, nanocircuits and strong 3D composites using SWNTs.
Bibliographic reference |
Terrones, Mauricio ; Charlier, Jean-Christophe ; Banhart, F. ; Grobert, N. ; Terrones, Humberto ; et. al. Towards nanodevice fabrication: Joining and connecting single-walled carbon nanotubes. In: New Diamond and Frontier Carbon Technology : an international journal on newdiamond, frontier carbon and related materials, Vol. 12, no. 5, p. 315-323 (2002) |
Permanent URL |
http://hdl.handle.net/2078.1/41538 |