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Modifying stainless steel surfaces with responsive polymers: effect of PS-PAA and PNIPAAM on cell adhesion and oil removal

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Callewaert, Maïté [UCL] Rouxhet, Paul [UCL] Boulange-Petermann, L

The treatment of stainless steel surfaces with responsive polymers was investigated using X-ray photoelectron spectroscopy and scanning electron microscopy. Poly (N-isopropylacrylamide) (PNIPAAM) is a temperature-sensitive polymer which is soluble in water below 32 degrees C (Lower Critical Solubility Temperature (LCST)) but collapses and aggregates above 32 degrees C. This polymer was adsorbed at 50 degrees C from solutions at different concentrations, followed by rinsing and different drying procedures. Thereby, a large variety of surface structures could be obtained, from smooth films to surfaces showing marked relief features due to residues of PNIPAAM aggregates. Two poly(styrene)b-poly(acrylic acid), PS-PAA, with different block lengths, were spin-coated on stainless steel and showed preferential exposure of PS blocks at the outermost surface. PNIPAAM-conditioning was shown to strongly reduce yeast cell adhesion and to facilitate the removal of oil soil due to its high water affinity and chain mobility below the LCST. PS-PAA coatings also reduced yeast cell adhesion; this may partly be due to a reorganization of the surface, leading to exposure of PAA chains in contact with water and thus to electrostatic repulsion of the yeast cells.

Document type Article de périodique (Journal article) – Article de recherche
Publication date 2005
Language Anglais
Journal information "Journal of Adhesion Science and Technology : the international journal of theoretical and basic aspects of adhesion science and its applications in all areas of technology" - Vol. 19, no. 9, p. 765-781 (2005)
Peer reviewed yes
Publisher Vsp Bv (Zeist)
issn 0169-4243
e-issn 1568-5616
Publication status Publié
Affiliation UCL
Keywords smart polymers ; responsive polymers ; poly(N-isopropylacrylamide) ; poly(styrene)b-poly(acrylic acid) ; coatings ; cell adhesion ; fouling ; cleaning
Links
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Bibliographic reference Callewaert, Maïté ; Rouxhet, Paul ; Boulange-Petermann, L. Modifying stainless steel surfaces with responsive polymers: effect of PS-PAA and PNIPAAM on cell adhesion and oil removal. In: Journal of Adhesion Science and Technology : the international journal of theoretical and basic aspects of adhesion science and its applications in all areas of technology, Vol. 19, no. 9, p. 765-781 (2005)
Permanent URL http://hdl.handle.net/2078.1/39092