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An in situ generated samarium complex as a practical catalyst for the efficient intramolecular hydroamination of non-activated alkenes

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Quinet, Coralie [UCL] Ates, Ali [UCL] Marko, Istvan [UCL]

Mixing Sml(2) and NaN(TMS)(2) generates in situ an efficient catalyst that promotes the intramolecular hychoamination of non-activated olefins. A wide range of aminoolefins can be cyclised smoothly using this simple protocol. Mechanistic studies led to the identification of the putative active catalyst. (c) 2008 Elsevier Ltd. All rights reserved.

Document type Article de périodique (Journal article) – Article de recherche
Access type Accès restreint
Publication date 2008
Language Anglais
Journal information "Tetrahedron Letters" - Vol. 49, no. 34, p. 5032-5035 (2008)
Peer reviewed yes
Publisher Pergamon-elsevier Science Ltd (Oxford)
issn 0040-4039
e-issn 1873-3581
Publication status Publié
Affiliation UCL - SC/CHIM - Département de chimie
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Bibliographic reference Quinet, Coralie ; Ates, Ali ; Marko, Istvan. An in situ generated samarium complex as a practical catalyst for the efficient intramolecular hydroamination of non-activated alkenes. In: Tetrahedron Letters, Vol. 49, no. 34, p. 5032-5035 (2008)
Permanent URL http://hdl.handle.net/2078.1/36436