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Synthesis of Five- and Six-Membered-Ring Compounds by Environmentally Friendly Radical Cyclizations Using Kolbe Electrolysis

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Lebreux, Frederic [UCL] Buzzo, Ferdinando [UCL] Marko, Istvan [UCL]

Substituted carbocycles, tetrahydrofurans, and tetrahydropyrans can be efficiently obtained from omega-unsaturated carboxylic acids. Our methodology involves a Kolbe decarboxylation followed by in intramolecular radical cyclization and a radical-radical cross-coupling process.

Document type Article de périodique (Journal article) – Article de recherche
Publication date 2008
Language Anglais
Journal information "Synlett : accounts and rapid communications in synthetic organic chemistry" - , no. 18, p. 2815-2820 (2008)
Peer reviewed yes
Publisher Georg Thieme Verlag Kg (Stuttgart)
issn 0936-5214
e-issn 1437-2096
Publication status Publié
Affiliation UCL - SC/CHIM - Département de chimie
Keywords cyclization ; electron transfer ; green chemistry ; heterocycles ; radical reactions
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Bibliographic reference Lebreux, Frederic ; Buzzo, Ferdinando ; Marko, Istvan. Synthesis of Five- and Six-Membered-Ring Compounds by Environmentally Friendly Radical Cyclizations Using Kolbe Electrolysis. In: Synlett : accounts and rapid communications in synthetic organic chemistry, , no. 18, p. 2815-2820 (2008)
Permanent URL http://hdl.handle.net/2078.1/36193