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Pentadienyl sulfoxide in triene synthesis. Efficient assembly of the Northern fragment of polycavernoside A

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Jourdain, Pierre [UCL] Philippart, Freddi [UCL] Dumeunier, Raphael Marko, Istvan [UCL]

Various polyunsaturated fragments, akin to the polycavernoside A Northern fragment, can be synthesized efficiently using as key steps a double Mislow-Braverman-Evans rearrangement of bis-allylic sulfoxides and a novel Julia-type 1,6-reductive elimination. (C) 2009 Elsevier Ltd. All rights reserved.

Document type Article de périodique (Journal article) – Article de recherche
Access type Accès restreint
Publication date 2009
Language Anglais
Journal information "Tetrahedron Letters" - Vol. 50, no. 26, p. 3366-3370 (2009)
Peer reviewed yes
Publisher Pergamon-elsevier Science Ltd (Oxford)
issn 0040-4039
e-issn 1873-3581
Publication status Publié
Affiliation UCL - SC/CHIM - Département de chimie
Links
Bibliographic reference Jourdain, Pierre ; Philippart, Freddi ; Dumeunier, Raphael ; Marko, Istvan. Pentadienyl sulfoxide in triene synthesis. Efficient assembly of the Northern fragment of polycavernoside A. In: Tetrahedron Letters, Vol. 50, no. 26, p. 3366-3370 (2009)
Permanent URL http://hdl.handle.net/2078.1/35522