The association of kinetic studies, DFT calculations and 1H–7Li NMR analyses allowed the control of the cyclo-ATRP of PEG9DMA and the production of polymethacrylate pseudo crown-ethers of various molar masses. Their potential to act as a solid-state polymer electrolyte in Li-ion batteries has been highlighted and may come from the supramolecular organization of the cyclo-PEG forming a Li+ diffusion channel.
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Bibliographic reference
Moins, Sébastien ; Martins, José ; Krumpmann, Arnaud ; Lemaur, Vincent ; Cornil, Jérôme ; et. al. Potential of polymethacrylate pseudo crown ethers as solid state polymer electrolytes. In: Chemical Communications, Vol. 53, p. 6899